间歇共沸精馏操作方式的改进研究-制药工程专业论文.docxVIP

中文摘要间歇共沸精馏是分离共沸物的一种方法，适用于化工、制药、溶剂回收、天 中文摘要 间歇共沸精馏是分离共沸物的一种方法，适用于化工、制药、溶剂回收、天 然产物提取等产量小，品种多的行业，因此间歇共沸精馏近年来已成为非常活跃 的研究和开发领域。 本文改变原有的间歇共沸精馏挟带剂的回流位置，即将挟带剂塔顶回流改为 塔釜回流，以乙醇一水(正己烷为挟带剂)为待分离物系在玻璃精馏塔上对间歇 共沸精馏过程进行了实验研究。 将塔釜回流的间歇共沸精馏与常规操作方式进行比较，考察了回流比、挟带 剂加入量等操作参数对过程的影响。结果表明，改进的间歇共沸精馏操作方式具 有可行性，与常规操作方式相比，在相同条件下，具有操作控制方便、产品收率 和产品纯度较高等优点，并克服挟带剂塔顶回流的一些不足：如塔身较高的精馏 塔，塔顶回流操作Iij难。 另外，采用改进的两点隐含法求解描述挟带剂塔釜回流的间歇共沸精馏过程 平衡级恒摩尔持液模型的非线性刚性方程组。将以上间歇共沸精馏实验数据对该 模型求解的计算结果进行了比较，实验值与计算值基本吻合。 关键词： 间歇共沸精馏 回流 操作方式 模拟 ABSTRACTBatch ABSTRACT Batch azeotropic distillation is used to separate azeotropic mixtures．Because it has both advantages of batch distillation and azeotropic distillation，batch azeotropic distillation has been becoming more and more important for the products of small scale and high extra value，such as the fine chemicals，pharmaceuticals and SO on． In this paper,the operation mode of regular batch azeotropic distillation is promoted and entrainer is reflux at the bottom．One experiment for the separation of ethanol and water using hexane as entrainer in the promoted batch azeotropic distillation Was discussed． The experimental data were compared with those under the same operation condition in regular batch azeotropic distillation．The effect of some key operation parameters such as the reflux ratio，the volume of entrainer consumed on the separation processes Was discussed．The results show that there are，in new mode， more advantages such as easier control of the process，higher yield of the distillate，etc． The promoted mode also overcomes some difficulties which meet in regular mode： the top reflux iS hard to control in higher distillate tower． Besides，the nonlinear stiff differential equations of the equilibrium mode describing batch azeotropic distillation are well solved by the modified two—point implicit integration method．The simulated results and the above experimental data show good agrcement． Key words：Batch azeotropic distillation Reflux Operation mode Simulation 独创性声明本人声明所呈交的学位论文是本