贱金属氧化物涂层电极制备与消毒发生器的开发-材料学专业论文.docxVIP

北京科技人学硕十学何论文摘 北京科技人学硕十学何论文 摘 要 本文采用SEM、XRD、电化学阻抗谱(E1S)、极化曲线，循环伏安曲线及加速寿 命电化学测试等方法探讨了制备方法、工艺、涂层成分等对贱会属氧化物涂层的形貌和 性能的影响因素，确定出最佳制备工艺，并应用贱会属氧化物涂层电极开展了在稀盐水 中电解生成消毒用NaCIO研究。 研究结果表明，热分解法制备的Ti／Mn02涂层电极其导电性和电催化性能与电沉积 法制备的MnOz涂层电极相比，有了显著的提高。涂液的浓度、烧结温度、烧结时问等 对热分解法制备Ti／MnCh涂层电极的电催化性能、稳定性有显著的影响。烧结温度为 350。C，烧结时问30 min涂覆lmoldm’Mn(N03h溶液制备的Ti／MnCh阳极具有最好的 析氯及析氧电催化性能，在H2s04中的加速寿命达到32h。添加snsb、h02、Ni2C004 等中『甘J层可以显著提高Ti／Mn02涂层阳极的加速寿命并改善了其电催化性能。 SbOx+Sn02的引入，对电极表面活性反应点数目影响不大，但基体和涂层I日J的接触电阻 从120hman。降低至4．30hmcm-2，电解液和新生的氧气侵入钛基体的通道受到阻隔和迟 缓，有效延缓了接触电阻的升高，使得Ti基Mn02电极的加速寿命从32h升高至140h, 并且电极的电催化性能也有了显著提高。 对制备的Ti／SnSb／Mn02涂层电极，开展了电解低浓度NaCl生成NaCl0的研究， 并确定了阴阳电极面积比、电解时间、温度、盐浓度、电流密度等参数。温度200c， 阳极面积为6眦2，电流密度20Adm-2时，电解609L1NaCI生成NaCl0的有效氯的电流 效率为80．1％，生成速度为22．26ingrainl。 关键词：二氧化锰电极，稳定性，电催化性，中间层，次氯酸钠 北京科技大学硕十学伊论文Preparation 北京科技大学硕十学伊论文 Preparation ofBase Metallic Oxide Coating Electrode and Researches on Disinfection Generator Abstract Factors influenced the stability and electro-catalytic activity such as preparation method， technique,composition,temperature were investigated and determined by ways ofSEM，Ⅺ皿 EIS，polarization curve,cyclic volt-metric and accelerated life test．Prepared base metallic oxide electrode was utilized to research the mles of the production of sodium hypochlorite,a highly effective sanifizer． Results indicated that Ti based mangancse dioxide prepared by thermal decomposition was more suitable for utilization as electrode material than it produced by electro-deposition． MnOz electrode prepared by decompounding l moldm-j Mn(N03h at annealmg temperamre of 350℃衙30min had the best chlorine evolution properties and stability．Electro-catalytic a曲vity and stability can be evidently improved by adding intermediate layers such as SnSb、 Ir02、Ni2C004Ti based MnOz anode with Sn_Sb intermediates showed excellent stability and hi曲er electr0_eatalytic activity,while its cost was comparatively low when compared with k02 intermediates．by introduction of SbOx+Sn02 intermediate layer,resistance beh