焦炉煤气脱硫技术的分析-化学工程专业论文.docxVIP

摘 摘 要 焦炉煤气中的硫化氢是一种非常有害的物质，在煤气使用前必须将其除掉。本 文阐述了国内外焦炉煤气净化工艺的发展、研究现状及焦炉煤气脱硫的意义。详细 介绍了湿式吸收工艺中的氨水法、单乙醇胺法、真空碳酸盐法和湿式氧化工艺中的 苦味酸法、萘醌二磺酸法、PDS法、HPF法等几种常见的焦炉煤气脱硫方法，重点说 明了这些脱硫方法的工艺流程、脱硫原理及其工艺特点。并对焦炉煤气脱硫方法进 行评述，分析比较了几种主要煤气脱硫技术特点。从碱源及工艺等方面考虑，并结 合我厂实际情况，选择了HPF法作为我厂脱硫工艺。针对该工艺，探讨了温度、脱 硫液中氨含量、催化剂浓度和双盐含量等对脱硫效率的影响。该工艺投入运行后， 各项指标达到预期效果。 关键词：焦炉煤气；脱硫；湿式吸收工艺；湿式氧化工艺 卜 The The Study on Pur i f icat ion TechnoIogy for Coke Oven Gas Abstract Hydrogen sulfide in coke oven gas is a very harmful substance which must be removed before use．In this paper,the present situation of the research and development on purification processes for coke oven gas at home and abroad were reviewed，and the significance of desulphurization is explained．Several conventional desulphurization processes are detailed described，such as ammonia process，sulfiban process and vacuum carbonate process in the wet absorption technology and Fumaks-Rhodacs process， Takahax process，Thylox process，Stretford process，PDS process and HPF process in the wet oxidation technology．The techniques flows，the theory of desulphurization and the techniques characteristics of them as key points were illuminated．The techniques characteristics of several purification processes for coke oven gas iS analyzed and compared．Comidering the sogrce of alkali and technology and combining the practical condition of our factory,HPF process is selected as desulphurization process．Aim at the technology,desulphurization efficiency affected by the factors such as temperature， ammonia content of desulphurization liquid，activator consistency and double salt content etc．is妇ussnd．Every anticipated target is achieved after the technology is lanced into function． Key words：coke oven gas；desulphurization；wet absorption technology：wet oxidation technology 独创性说明作者郑重声明：本硕士学位论文是我个人在导师指导下进行的研 独创性说明 作者郑重声明：本硕士学位论文是我个人在导师指导下进行的研 究工作及取得研究成果。尽我所知，除了文中特别加以标注和致谢的 地方外，论文中不包含其他人已经发表或撰写的研究成果，也不包含 为获得大连理工大学或者其他单位的学位或证书所使用过的材料。与 我一同工作的同志对本研究所做的贡献均已在论文中做了明确的说 明并表示了谢意。 作者签名：姻塑趁日期：