角蛋白PVA共混溶液性能及纤维成形机理-纺织工程专业论文.docxVIP

中原工学 中原工学院硕士学位论文 摘要 II II Keratin/PVA blend solution properties and fiber forming mechanism Specialty: Textile engineering Name: Qi Meng Supervisor: Professor Liu Rangtong Abstract As the source of wool fiber is limited, and the wool textile enterprises produced inferior wool and waste with rising, On one hand, we hope to have good wool alternative raw materials, on the other hand, also want to change waste into treasure, this idea has attracted the attention of all walks of life. Fibrosis regeneration of waste hair which is an effective solution, is the keratin solution of waste hair was spinning reuse, the key point is that the excellent solution spinning and spinning performance. This topic is based on the point of all this approach, using cytokeratin and polyvinyl alcohol their blend solution as the research object, launches the research from three aspects.Firstly,we use the rheometer test the rheological properties of the keratin / PVA blend solution,and examine the different molecular weight PVA, keratin /PVA different ratio, temperature on the rheological properties of the blend solution.Secondly, by observing the extrusion processing and diffusion process, we find the impact the fiber extrudate swell and diffusion coefficient factors with the relationship between the spun fiber into yarn properties.Lastly, we observe the surface shape and cross-section morphology of the blend fiber by scanning electron microscope,and conduct the mechanical characterization, and then study the thermal stability of the fibers and the component by thermal gravimetric analysis. The results show that: rheological test, When polyvinyl alcohol with low molecular weight, blending ratio of not more than 3:7, coagulation bath temperature less than 50 degrees, the processability of keratin and polyvinyl alcohol solution can be good, good spinning property .The spinning process, the spinneret diameter is 0.1mm, spinning speed not higher than 80r/min, free elastic spinning solution can b