结合分形理论的水泥絮凝研究-材料学(土木)专业论文.docxVIP

大连理工大学硕士学位论文摘 大连理工大学硕士学位论文 摘 要 新拌水泥浆体中，水泥颗粒互相粘结形成包裹水的絮凝结构，严重影响了混凝土的 工作性和强度。目前国内外对于水泥絮凝方面的认识还不够全面，对絮凝颗粒的大小、 分布、形貌及特性等形态学方面的研究较少，对絮凝结构的破坏作用也仅仅从宏观指标 去衡量。针对这一现状，本文重点研究了絮凝结构的微观形貌及特性，并把微观结构与 宏观性质联系起来，以利于全面认识絮凝，更好地指导水泥的生产与工程应用。 本文以激光粒度分析仪、光学显微镜作为主要试验工具，以“分形”作为理论基础， 对水泥浆体中水泥絮凝颗粒的空间分布及絮凝结构微观形貌进行了定量分析和评价，并 建立了与分形特征相关的水泥用水量数学模型。采用对比试验，讨论了水泥絮凝形成机 理。通过对水泥浆体连续水化的微观分析，探讨了絮凝的存在对水泥水化的影响。 结果表明：构成水泥浆体的基本单元为絮凝结构，絮凝结构卷裹了大量的水分并以 点一点形式相连接，并存在于水泥水化的全过程，会阻碍水化产物的生长扩散；水泥絮 凝颗粒的空间分布、絮凝结构微观形貌都具有很好的自相似特征，属于典型的分形结构： 分形特征与水泥宏观性质，如净浆流动度、比表面积、减水率之间存在较好的相关性。 本文的基础性研究工作，为水泥絮凝领域微观结构与宏观性质的联系奠定了基础， 为全面认识水泥，更深入的研究开辟了一条新途径。 关键词：水泥；絮凝；分形维数 结合分形理论的水泥絮凝研究Study 结合分形理论的水泥絮凝研究 Study on Flocculated Cemem Combining with Fractal Theory Abstract Flocculated cement slzucture enclosing lots ofwater can be found in cA：mcnt paste，which will influence fluidity and strength of concrete．At present，flocculated cement field lacks of leseafch，having not found something about size,distribution,microcosmic as well as properties of flocculation particles．Cement fluidity is the only macroscopically standard for flocculation．In order to change this condition,this paper fred a new way to research flocculated cement from angle of microscopic structure and build a relationship of macroscopically property and microcosmic slracture． Laser Fineness Gage and optical microscope arc test tools and fractal is the base of theory．Distribution of flocculated cement in three-dimension space and microcosmic pattern are researched,at the salne time a math model is built．Mechanism of flocculated cement has been concluded by comparison test．Relationship between flocculation structure and cement hydration are found through observation． Results show that：Flocculated cement is element of cement paste and encloses a larger number ofwater．It Can affect cement hydratiom Flocculated cement distrib埘on and particle itself are self-similar structLtre,they belong typical fractal structure．The author calculates the fraetal dimensions and fred the rule of frac