金、铂纳米粒子的气液界面组装-物理化学专业论文.docxVIP

米子组装膜在染料敏化太阳能电池方面的应用。 米子组装膜在染料敏化太阳能电池方面的应用。 3、空气氛下加热亚锡离子保护的Au溶胶，可在气一液界面迅 速组装出致密光亮的Au纳米粒子薄膜，研究了金纳米粒子组装膜对 乙醇或葡糖糖的电催化。 关键词：自组装、气．液界面、蒸汽、表面增强拉曼散射、电催化、 湿润性、染料敏化太阳能电池 Il ABSTRACTMaterials ABSTRACT Materials by self-assembly of nanoparticles(NPs)have attracted considerable attention on account of their wide applications in energy resources，catalysis，optics，electronics，sensing，superhydrophobic biominetics，and biomedicine．Although there have been a number of strategies on nanoassembly,exploring new ways of assembly to synthesize two or three dimensional functioned metal nanoparticle films is still of significance in both fundamental research and practical applications．In this thesis，we have developed some new methods to assemble Au and Pt nanoparticles at the air-water interface either by using the vapor of weak acidic electrolyte or dodecyl mercaptane，or by heating the colloid．We also investigated the applications of the prepared films in SERS，electrocatalysis，wettability,and dye-sensitized solar cells．The main contents are as follows： (1)A concentration gradient of H+was established by contacting the colloids of Au and Pt with the vapor of formic acid，which induced the assembly of colloidal nanoparticles of gold and platinum to form close—packed thin films at the air-water interface．The morphologies of films Call be adjusted by controlling the assembly time．Comparative investigations were performed either using other volatile electrolytes like weak acetic acid and stronger hydrochloric acid or adding formic acid directly directly into the colloids．We manifested the assembly mechanism at the 1 air-water interface by a designed colorimetric method and the HNMR． We also showed the applications of the assembled film of Au NPs in SERS． (2)By contacting the vapor of dodecyl mercaptane with the colloid of citrate—Au，citrate．Pt or Sn2+．Au NPs，self-assembly of col loidal NPs took place at the air-water interface as a result of ligand exchange that occurred at the interface，form