金属硫族化合物纳米颗粒的制备与非线性光学性质研究-等离子体物理专业论文.docxVIP

万方数据 万方数据 摘 要 本论文以有机溶剂热法制备了金属硫族化合物纳米颗粒，并对其微观结构和 非线性光学性质进行了表征，探讨了不同分散剂作用下硫化铅量子点所表现出来 的不同的微观结构和非线性光学响应机制。还设计了一种制备硒化银量子点的工 艺流程，并对其微结构和光学非线性进行了研究，发现了一种之前未被报道过的 光致再生长效应，讨论了这种效应对材料为结构和非线性光学效应的影响，并对 其产生机制进行了阐述。主要内容概括如下： 1. 以有机溶剂热法为基础，设计制备了 PbS 量子点和 Ag2Se 量子点。其中， 根据分散剂的不同，PbS 量子点分为 PbS-甲苯量子点，PbS 正己烷量子点和 PbS 四氯化碳量子点。 2. 利用高分辨透射电子显微镜和紫外可见吸收光谱仪对上述量子点的微结 构和吸收光谱结构进行了分析，讨论了分散剂对于 PbS 量子点晶粒生长和激子吸 收产生的影响。发现了 Ag2Se 量子点的再生长现象。 3. 利用拉曼光谱研究了上述量子点的分子振动模式，比较了三种不同分散剂 下 PbS 量子点拉曼吸收峰的变化，研究了 Ag2Se 量子点的拉曼散射特征曲线。 4. 利用单光束 Z 扫描技术研究了样品的非线性光学性质并计算出了 PbS 量子 点的非线性折射系数。观察并阐述了光致再生长效应对 Ag2Se 量子点非线性光学 响应的作用。 关键词：金属硫族化合物；纳米颗粒；非线性光学；再生长 I Abstract The dissertation focused on the study of the micro-structure and nonlinear optical properties of the colloidal metal chalcogenide quantum dots(Qdots) synthesized via solvothermal method and discussed how dispersant influenced the local structure and the nonlinear optical response of the PbS quantum dots. We also designed a wet chemical process to fabricate Ag2Se quantum dots and studied its micro-structure and nonlinear optical properties as well, in which, we found a phenomenon that haven`t been published yet--the regrowth kinetics and discussed how this kinetics affected the microstructure and the nonlinear optical properties of Ag2Se quantum dots. The main work is summarized as follows: Synthesized the PbS and Ag2Se quantum dots based on solvothermal method. Classified by the dispersant, the PbS quantum dots can be listed as PbS-toluene Qdots, PbS-hexane Qdots and PbS-CTC Qdots. Investigated the microstructure and absorption spectrum of the Qdots mentioned above by HRTEM technology and UV-Vis spectrophotometer, and discussed the influence that dispersant leaded to the Qdots. Discovered the regrowth kinetics of the Ag2Se Qdots. By using the Raman spectroscopy, we studied the molecular vibrational modes of the above Qdots and investigated the difference of the Raman spectrum of the PbS Qdots synthesized by three kinds of dispersant. Studied the Raman scattering