金属有机框架派生的多孔碳材料在样品前处理技术中的应用-分析化学专业论文.docxVIP

3．通过赢接碳化含铁金属有机框架MIL．53制备了嵌入磁性Fe的多孔碳材 3．通过赢接碳化含铁金属有机框架MIL．53制备了嵌入磁性Fe的多孔碳材 料(MIL．53．C)。制备的MIL．53．C具有高比表面积和强磁性。通过扫描电子显微 镜、透射电子显微镜、振动样品磁强计和氮气吸附方法对MIL．53．C的结构、形 态、磁力性质和多孔性进行了表征。将MIL．53．C作为磁性固相萃取剂萃取水样 和人类尿液中的三种激素，并用高效液相色谱．紫外检测器进行检测。该方法在 水和尿样中的线性范围分别为0．02—100．0 ng／mL和O．5．100．0 ng／mL。LOD(S／N=3) 分别为0．005-0．01 ng／mL和0．1_0．3 ng／mL。定量限(LOQ)(．S小=lO)分别为 0．01 5—0．030 ng／mL和0．3—0．9 ng／mL。 4．通过一步碳化含铁金属有机框架(MIL．53)制备了磁性多孔碳0垤IL．53．C)。 制备的MIL．53．C具有高比表面积，大孔体积和良好的磁性。文章将MIL．53．C 用作磁性固相萃取吸附剂并与高效液相色谱联用测定果汁和牛奶中的内分泌干 扰素(EDCs)。在最优条件下，实验具有良好的线性，线性相关系数高于0．9995。 果汁样品和牛奶样品的LOD(S腓--3)分别为O．05．0．10 ng／mL和0．10．0．20 ng／mL。 加标回收率在87．3％到108．7％之间。结果表明MIL．53．C对痕量EDCs表现出了 良好的吸附效果。 关键词：金属有机框架派生的多孔碳；固相萃取；磁性固相萃取；高效液相色谱； 氨基甲酸酯：烟碱；激素；内分泌干扰素 万方数据 Application Application of Metal-Organic Framework Derived Porous Carbon Materials in Sample Preparation Technology Name：Hao Lin Supervisor：Wang Zhi Major：Analytical Chemistry Abstract Due to the low concentration of the analytes(always in lxg or ng level)， complexity of the matrix(there are many different kinds of pollutants，which have serious interferences to analytes)．analytes preconcentration and isolation from the sample matrix prior to their determination are often necessary．Sample preparation is considered as the most critical step in an overall analytical process． In recent years，the solid phase extraction(SPE)and magnetic solid—phase extraction(MSPE)have been developed．Compared with the traditional liquid—liquid extraction(LLE)sample preparation technology,the SPE and MSPE can overcome the disadvantages of LLE，such as time-consuming and large volumes of toxic organic solvents consumption． With the wide application of SPE and MSPE technology,the exploration of new types of adsorbents to improve the extraction efficiency for different analytes has become an active research field in analytical chemistry．The adsorbents with high stability,high selectivity,high extraction ability have attracted more and more attention．Metal-organic frameworks derived nanoporo