浸没循环撞击流反应器中的流动与混合-化学工程专业论文.docxVIP

The The present paper reported a fundamental study on flow and mixing in a submerged circulative impinging stream reactor(SCISR)，which is a uew reactor patented by professor Wu Yuan． The residence time distribution(RTD)in SCISR is investigated by all electroconductivity input-response technique with KCl solution as the tracer．The experimental results certify that the proposed flow configuration of perfect mixing and plug flow in series with circulation， which is one of the distinguishing features of SCISR，and the corresponding RTD model are feasible． Micromixing in SCISR is investigated with the reactions between 1-naphthol(A)and diazotised sulphanilic acid(B)to produce monoazo dye(R)and biazotized sulfanilic acid(S)with known rate constants as the working reactions The micromixing time constant，tM is estimated according to the variation of the selectivity of S，the product the second reaction of slow rate，with the rotary speed of the propeller．The results show that tM is under l 92 ms when the rotating speed，一，exceeds 450 rpm at 298 K，while becomes 1ess than 87 ms when n exceeds 11 00 rpm at 308 K，suggesting that show the micromixing is promoted very effectively in the impingement zone AISO，the influences of rotary speed and the volume ratio of solutions A to B on micromixing and the relationship between the initial concentration of B，Cm，and the segregation index，Xs，are studied．The results show that tlle both increasing in rotary speed and decreasing in the volume ratio promote mieromixing，while the relationship between CB0， and B confirms that the micromixing time is defined essentially by the rotary speed． A study iS made for comparison bptween SCISR and the traditional stirred taIll(reactor(STR)in order to understand the micromixing nature further．The results show that SCISR greatly prior to STR with the same conditions of the specific．effective power inputted and the same mean ll 摘要 摘要 residence time． Finally,the velocity flow at the outlet of the drawing tube