含双酰肼的芳氧苯氧丙酸类衍生物的合成与生物活性-现代农药.PDF

第16 卷 第5 期 现代农药 Vol.16 No.5 2017 年10 月 Modern Agrochemicals Oct. 2017 ◆ 创制与生测 ◆ 含双酰肼的芳氧苯氧丙酸类衍生物的 合成与生物活性 杨子辉，田 昊* ，张 莉 （ 山东金华海生物开发有限公司，济南 251400） 摘要： 喹禾灵等芳氧苯氧羧酸类除草剂的结构为基础，合成了 含双酰肼的芳氧苯氧丙酸类 以 3个 衍生物，其化学结构经1 和高分辨质谱确证。 初步除草活性表明，在 2有效成分用量 H NMR 150 g/hm 下，其中 新化合物对单子叶杂草看麦娘、棒头草等具有较好的抑制活性，抑制率达到 2个 80%。 关键词：芳氧苯氧丙酸类；双酰肼结构；新化合物；合成；除草活性 中图分类号： 文献标志码： ： TQ 450.1 A doi 10.3969/j.issn.1671-5284.2017.05.003 Synthesis and Herbicidal Activity of 2-(4-Aryloxyphenoxy)propionic Derivatives Containing Diacylhydrazine Group YANG Zi-hui, TIAN Hao*, ZHANG Li (Shandong Jinhuahai Biotechnology Co., Ltd., Jinan 251400, China) Abstract: Three novel 2-(4-aryloxyphenoxy)propionic derivatives containing diacylhydrazine group were synthesized based on the structure of aryloxyphenoxypropionic herbicides such as quizalofop-ethyl. Their structures were confirmed by 1 NMR, HRMS. The preliminary bioassay results showed that the two title compounds 5a, 5c had some herbicidal activities H 2 at the dosage of 150 g/hm , the herbicidal activities were more than 80% on Alopecurus aequalis and Polypogon fugax. Key words: aryloxyphenoxypropionic; diacylhydrazine; new compound; synthesis; herbicidal activity 芳氧苯氧丙酸类除草剂为乙酰辅酶A羧化酶抑 物，将双酰肼基团引入芳氧苯氧丙酸类分子结构 制剂，用于防除一年生和多年生禾本科