锑磷在膨润土和高岭土的竞争吸附①-土壤.PDF

土 壤 (Soils), 2017, 49(3): 492–499 DOI: 10.13758/ki.tr.2017.03.010 锑/磷在膨润土和高岭土的竞争吸附① * (/ 100081) / (Sb/P) pH Sb P Langmuir Freundlich (R2 = 0.945 0 ~ 0.998 3, P 0.000 1) P Sb (Qmax)0.86 10.21 mmol/kg(Sb P)0.64 2.61 mmol/kg(P Sb) Sb P (K)1.47 7.47 L/mmol(P Sb)0.68 2.34 L/mmol(Sb P)Sb P pH pH (R2 0.994P 0.000 1)Sb/P P (q = 0.36 mmol/kg,k = 0.064 6 kg/(mmol·min))Sb (q = 0.19 mmol/kg e 2 e k = 0.076 9 kg/(mmol·min)) P (q = 0.66 mmol/kgk = 0.591 kg/(mmol·min))Sb 2 e 2 [q = 0.39 mmol/kg k = 0.052 4 kg/(mmol·min)] Sb P () e 2 P Sb () pH X131.3 S153.3 A (Sb) (As)Sb-Fe [1] [8-11] [12] Sb Sb “ (40 )Sb ”[2] Sb ( 80%)[3] [4]( )Sb 527 ~ 11 798 mg/kg Sb (P) 1 837 mg/kgSb 6.3 ~ 748 mg/kg[5] Sb Sb P Sb / Sb [13-15] Sb – Xi [16] Sb(OH) P Sb (III) 6 Canecka [17]Sb (V) P Sb P-Sb Sb [6-9]Sb (V) ( pH Sb (III)pH ) Sb P Sb Sb * (xum