氟硅改性纳米SiO2WPU杂化乳液超疏水涂层的制备.docVIP

改性纳米SiO2/聚氨酯乳液超疏水涂层的表面及力学性能研究 卫晓利, 张发兴* (四川理工学院化学工程学院，四川 自贡 643000) 摘要: 以氟硅偶联剂改性的SiO2纳米粒子，由双键封端的聚氨酯和硅氧烷封端的聚氨酯乳液复配乳液作为主要原料，制备了一种新型的有机－无机杂化的超疏水涂层。着重研究了SiO2纳米粒子含量和两种乳液的质量配比对涂层表面性能及力学性能的影响。研究表明：在聚氨酯涂层表面喷涂氟硅偶联剂改性的SiO2纳米粒子，使得涂层表面具有超疏水性的特性，而且随着SiO2纳米粒子含量的增加，涂层的粗糙度增强，疏水性增强，当SiO2纳米粒子的质量百分比增大到1.1%，涂层的表面能够达到超疏水的效果。乳液的质量配比对涂层的表面性能及力学性能也有重要的影响，随着乳液配比的增大，涂层的疏水性增强，拉伸强度和剥离强度有所减小，但断裂伸长却有所增强。 关键词: 改性纳米SiO2；聚氨酯乳液；超疏水涂层；表面性能 Surface and mechanical properties of modified nano - SiO2 / polyurethane emulsion super hydrophobic coating WEI Xiaoli ，ZHANG Faxing (Department of material and chemical engineering, Sichuan institute of technology ,Zigong, 643000) Abstract: In this study , a type of organic-inorganic hybrid super hydrophobic coating was prepared with modified nano - SiO2 by fluorine and silicone coupling agent ,and the polyurethane mixing emulsion as main raw materials which contain two kind of polyurethane emulsion sealed by double bond and silicone respectively. The influence of content of modified nano - SiO2 and the quality ratio of two kinds of emulsion on performance of coating surface and mechanical properties were studied. Research shows that: if modified nano - SiO2 by fluorine silicon coupling sprayed onto polyurethane coating surface was agent, the coating may has the characteristics of super hydrophobic surface. And with the increase of the content of modified nano - SiO2 coating roughness increased, enhanced hydrophobic, when the quality percentage of modified nano - SiO2 increases to 1.1%, the surface of the coating can achieve the effect of super hydrophobic. Ratio of the quality of the emulsion on the surface of the coating performance and mechanical performance has important influence, with the increase of the ratio of emulsion and coating of hydrophobic enhancement, the tensile strength and peel strength reduced, but the elongation at break is increased. Keyword: modified nano - SiO2; polyurethane mixing emulsion; super hydrophobic coating; Surface performa