十六烷基三甲基溴化铵改性沸石对水中CrⅥ的吸附去除率-硅酸盐学报.PDF

第 38 卷第 11 期 郝艳玲 等：坡缕石黏土吸附 Cu2+ 的动力学 · 2143 · 第 38 卷第 11 期 硅 酸 盐 学 报 Vol. 38 ，No. 11 2 0 1 0 年 1 1 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY November ，2010 十六烷基三甲基溴化铵改性沸石对水中Cr(Ⅵ) 的吸附去除率 杨慧芬，张伟娜，胡瑞娟 (北京科技大学土木与环境工程学院，北京 100083) 摘 要：以十六烷基三甲基溴化铵改性沸石为吸附材料，采用搅拌吸附方法研究了其对废水中 Cr(Ⅵ) 的吸附去除效果，并利用 X 射线衍射和红外光 谱分析了其吸附特征。结果表明：在改性沸石粒度(–0.25+0.15) mm 、用量 30 g/L、溶液初始pH = 6，在25 ℃搅拌吸附 30 min ，水中 Cr(Ⅵ) 的吸附去除 率达到 91% 以上。改性沸石对水中Cr(Ⅵ) 的吸附可用Langmuir 吸附等温线描述，每 100 g 改性沸石对 Cr(Ⅵ) 的饱和吸附量为26.53 mg 。 关键词：十六烷基三甲基溴化铵；改性沸石；吸附；铬(Ⅵ) ；饱和吸附量；废水 中图分类号：X703.1 ；TB321 文献标志码：A 文章编号：0454–5648(2010)11–2143–05 REMOVAL RATE OF Cr(Ⅵ) IN WASTEWATER ONTO CLINOPTOLOLITE MODIFIED BY CETYLTRIMETHYLAMMONIUM BROMIDE YANG Huifen，ZHANG Weina ，HU Ruijuan (Civil and Environmental Engineering school, University of Science and Technology Beijing, Beijing 100083, China) Abstract: Adsorption removal rate of Cr(Ⅵ) in wastewater onto clinoptilolite modified by cetyltrimethylammonium bromide (CTMAB, C + − H (CH ) N -Br ) as an adsorption material, was studied with stirring method. Adsorption characteristics were analyzed 16 33 3 3 by X-ray diffraction and infrared absorption spectra. The results show that removal rate of Cr(Ⅵ) in wastewater is more than 91% when the clinoptilolite size is (–0.25+0.15) mm, with clinoptilolite usage of 30 g/L, adsorption time of 30 min at initial pH = 6 of wastewater and temperature of 25 ℃. The adsorption of Cr(Ⅵ) onto modified clinoptilolite can be expressed by Langmiur adsorption isotherm model. The saturated adsorption amount of Cr(Ⅵ) is 26.53 mg per 100 g modified clinoptil