四苯基对苯二酚双磷酸酯的合成与应用研究-南京师范大学学报.PDF

32 2 () Vol. 32 No. 2 2009 6 JOURNAL OF NANJING NORMAL UNIVERSITY (Natural Science Edition) Jun, 2009 杨智中, 严 慧, 杨锦飞 (, 210097) [] (TPP), TPP . , : (TPP) 211, 130~ 140 , 05 h; 160~ 170 , 05 h;, 92%., ; ;, . [] , ,, [] TQ225. 24 [] A [] 2009) Synthesis of Quinol Bis(D iphenyl Phosphate) Flam e Retardant Yang Zhizhong, Yan H ui, Yang infei (School of Che istry and Environ ental Science, NanjingNor alUniversity, Nanjing 210097, China) Abstract: Quinol bis( diphenyl phosphate) was synthesized fro phosphous oxychloride, p dihydroxybenzene and phe nol. T riphenyl phosphate ( TPP) was prepared by the reaction of phenolwith phosphous oxychloride. TPPwas then al lowed to reactwith quinol to give theproduct. The effects of process para eters, such as olar ratio, reaction te pere ture and catalyst on theyieldwere studied respectively, and the suitable synthesis conditionswere defined as follows: the olar ratio of triphenylphosphate and quinol is 211. In the first step, the reaction te peraturewas 130- 140 , and the reaction ti ewas 05 hour. In the second step, the reaction te perature was 160- 170 , and the reaction ti e was 05 hour. A lCl was thebest catalyst, and its dosagewas 1% of the a ount of quinol. The yield reached 92%. The 3 structure of the productwas defined by FT- IR. The quality indexes of the product can reach the indexes of the oversea product. K ey words: quinol, quinolbis( diphenyl phosphate), fla e retardant, synthesis ., ,, . . , , ., PU ( )PC()ABS( )PET()SAN( - )PP(). : , , , ,. , : : (BE2007050). : , , : . E ail: yangjinfei@ njnu. edu. cn