电解抛光态690TT合金经不同时间浸泡后表面氧化膜结构分析.pdfVIP

47 7 Vol.47 No.7 2011 7 831—838 ACTA METALLURGICA SINICA Jul. 2011 pp.831–838 690TT ∗ Æ (, 110016) AFM, SEM, TEM, EDS XPS 690TT B Li, H2 . , , ; Ni . 720, 1440 2160 h , : Ni Fe ; Ni ; Cr . . 690TT . 2160 h , , . 690TT , , , , TG172.82 A 0412−1961(2011)07−0831−08 ANALYSES OF SURFACE OXIDE FILMS ON ELECTRO- POLISHED ALLOY 690TT AFTER IMMERSION FOR DIFFERENT TIMES ZHANG Zhiming, WANG Jianqiu, HAN En–Hou, KE Wei State Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 Correspondent: WANG Jianqiu, professor, Tel: (024 E-mail: wangjianqiu@imr.ac.cn Supported by National Basic Research Program of China (No.2011CB610502) and National Natural Science Foundation of China (No Manuscript received 2011–05–12, in revised form 2011–06–10 ABSTRACT The corrosion of Ni base alloys in high temperature and high pressure water is affected by samples surface statuses. The morphologies and structures of surface oxide films grown on electropolished (EP) alloy 690TT after immersion in the simulated hydrogenated primary water of pressured water reactors (PWRs) for different times were analyzed by AFM, SEM, TEM, EDS and XPS. After immersion for 15 and 35 h, the EP alloy 690TT samples were covered with columnar oxides. With the increase of the immersion time, the sample surfaces were covered with scattered big oxide particles and loose needle–like oxides. Regardless of the immersion