废碱液催化氧化脱硫工艺探究.pdfVIP

第46卷第9期 应　 用　 化　 工 Vol.46 No.9 2017年9月 Applied Chemical Industry Sep.2017 废碱液催化氧化脱硫工艺研究 沈寒晰,张金峰,吴素芳,卢美旭 (陕西省石油化工研究设计院陕西省石油精细化学品重点实验室,陕西 西安　 710054) 摘　 要:以硫酸亚铁、硝酸锰为活性物制备铁锰复合催化剂,对乙烯废碱液进行常压空气催化氧化脱硫,考察了反 应温度、反应时间、曝气量、催化剂浓度等因素对脱硫效率的影响。 结果表明,在反应温度50 ℃,反应时间20 min, 2- 曝气量40 L/ h,催化剂浓度10 mg/ L条件下,复合催化剂具有很好的催化活性,S 的转化率达99.7%。 关键词:废碱液;催化氧化;脱硫;工艺 中图分类号:TQ085;TQ 125　 　 文献标识码:A　 　 文章编号:1671-3206(2017)09-1717-03 Study and optimization of catalytic oxidation technology in spent caustic desulfurization SHEN Han-xi,ZHANGJin-feng,WUSu-fang,LUMei-xu (Shaanxi Key Laboratory of Fine Petroleum Chemicals,Shaanxi Research Design Institute of Petroleum and Chemical Industry,Xi’an710054,China) Abstract:Thecatalystwaspreparedbyusingironsaltandmanganesesaltasactivematter.Usingthepre- pared catalyst,the ethylene pent caustic was oxidized at atmospheric pressure and low temperature by using air as oxidant.The influence of reaction temperature,reaction time,air,catalyst concentration etc. on the desulfurization efficiency was investigated.The result showed that the reaction temperature was 50 ℃,the reaction time was 20 min,air was40 L/ h,the catalyst concentration was 10 mg/ L.The pre- 2- pared composite catalystshavegoodcatalyticactivity,theS conversionratewas99.7%.Thetechnology has some advantages,for example,use amount of catalyst wasvery low,reaction timewas short.The tech- nology achieved good effect in the chemical plant,it has a good application prospect. Key words:spent caustic;catalytic oxidation;desulfurization