成膜性纳米微乳液封堵剂的制备与评价.pdfVIP

47 1 Vol.47 No.1 2018 1 Applied Chemical Industry Jan.2018 ，， （ ， 710065 ） ：（St）、（MA）（AM），， ，。 ：span80∶tween80 ＝2∶1（）， St∶MA∶AM ＝3∶1∶2（），25％，2％，60 ℃， 4 h。 125.5 nm，；， 290 ℃，；3％ ，90 ℃16 h ，， ，API 2 mL，FLHTHP（30 min） 6.0 mL，，。 ：；；； ：TQ 316.33 ；TQ 203.3 ：A ：1671 －3206（2018）01 －0092 －04 Preparation and evaluation of film-forming nano microemulsion plugging agent YU Hong -j iang ，TA Dan ，XIONG Xun-yu （School of Chemistry and Chemical Engineering of Xi ’an Petroleum University ，Xi’an 710065 ，China） Abstract ：Styrene（St），methyl acrylate（MA） and acrylamide（AM） were used as reaction monomers ，and azodiisobutyronitrile was used as initiator ，the microemulsion plugging agent was synthesized by reverse microemulsion polymerization.The best condition of synthetic reaction were as follows ：fixed the emulsifier ratio of span80∶tween80 was 2∶1，the mass ratio of St∶MA∶AM was 3∶1∶2 ，the total monomer concentra- tion was 25％，the amount of initiator was 2％ based on total monomers mass ，the reaction temperature was 60 ℃，the reaction time was 4 h，the median diameter of the plugging agent was 125.5 nm，which meets the requirements of plugging the microcracks of shale ；the decomposition temperature of nano plug- ging agent was about 290 ℃，and the thermal stability is good.After adding 3％ of the plugging agent into the drilling fluid system ，90 ℃ hot roll 16 h，the viscosity and shearing force changed little and the rheo - logical property was stable ，and the loss of API was only 2 mL，its FLHTHP（30 min） was 6.0 mL.The nano plugging agent had excellent performance and good plugging effect . Key words ：film-forming；nano m