铸铁文物复合气相缓蚀剂的复配与研究.PDF

第35 卷 第3 期 中国腐蚀与防护学报 Vol.35 No.3 2015 年6 月 Journal of Chinese Society for Corrosion and Protection Jun. 2015 铸铁文物复合气相缓蚀剂的复配与研究 滕 飞 井宇阳 胡 钢 北京大学考古文博学院 北京 100871 摘要：以碳酸环己胺(CHC) 为主体，通过与其它缓蚀剂复配，筛选出可用于铸铁文物保护的高效复合气相缓蚀 剂。用极化曲线，电化学阻抗谱和XPS 等手段研究了该复合气相缓蚀剂的缓蚀作用机理。结果表明：CHC 与 乌洛托品复配，具有良好的协同缓蚀效果，当乌洛托品与CHC 以1∶4 的质量比复配时，缓蚀率可达96.61% 。该 复合气相缓蚀剂是以抑制阳极反应为主的混合型缓蚀剂，能够和铸铁发生化学吸附而形成缓蚀性能良好的保 护膜。 关键词：复合气相缓蚀剂 铸铁 缓蚀机理 中图分类号：TG 174.42 文献标识码：A 文章编号：1005-4537(2015)03-0265-06 Research of Compound Volatile Corrosion Inhibitors for Cast Iron Relics TENG Fei, JING Yuyang, HU Gang School of Archaeology and Museology, Peking University, Beijing 100871, China Abstract: Applying volatile corrosion inhibitors is an effective way to protect cast iron relics. Here- with several new formulas of compounds of cyclohexylamine carbonate (CHC) with various kinds of inhibitors were designed and prepared for cast iron. Then their performance of corrosion inhibi- tion was studied by means of electrochemical measurements and XPS. Results show among others that CHC with methenamine exhibits significant synergistic effect, i.e. a compound of mixed me- thenamine and CHC with a mass ratio 1∶4 exhibits the highest inhibition efficiency up to 96.61%. This mix-type compound inhibitor, which mainly suppressed the anodic reaction, could be chemi- cally absorbed on the cast iron surface to act as a well-functioned protective film for cast iron relics. Key words: compound volatile corrosion inhibitor, cast iron, inhibition mechanism 1 前言 用的缓蚀剂多为工业用品，专门针对铸铁文物的缓