硅酸盐水泥水化电阻率法和热量法的相关性-硅酸盐学报.PDF

第 46 卷第 5 期 硅 酸 盐 学 报 Vol. 46 ，No. 5 2 0 1 8 年 5 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY May ，2018 DOI ：10.14062/j.issn.0454-5648.2018.05.09 硅酸盐水泥水化电阻率法和热量法的相关性 田卒士，田 野，金南国，金贤玉 (浙江大学建筑工程学院，杭州 310058) 摘 要：电阻率法和热量法是研究水泥水化过程2 种常用的方法，但是由于温度条件的不同，这 2 种方法无法进行合理的比 较。考虑温度对电阻率和水化速率的双重影响，基于等效时间原理探讨了温度对电阻率变化率的放大效应、温度变化效应和 加速效应，建立了电阻率法和热量法的关系。理论分析与试验研究表明，电阻率法和热量法所确定的水化过程溶解期、加速 期和减速期在时间上具有一致性。在温度的多种影响因素中，加速效应是引起电阻率变化率主峰出现的最主要原因。 关键词：电阻率；水化放热；水化速率；水泥；温度；相关性 中图分类号：TQ172 文献标志码：A 文章编号：0454–5648(2018)05–0670–07 网络出版时间：2018–02–23 Relation Between Resistivity Method and Thermodynamic Method on Assessment of Portland Cement Hydration TIAN Zushi, TIAN Ye, JIN Nanguo , JIN Xianyu (College of Civil Engineering and Architecture, Zhejiang University, Hangzhou 310058, China) Abstract: Cement hydration process is commonly investigated via resistivity and thermodynamic measurements. However, the test results of the above methods cannot be compared reasonably due to their different temperature conditions. The influence of temperature on the resistivity and hydration rate was taken into consideration. Based on the equivalent time principle, the magnification, change and acceleration effects of temperature on the resistivity rate were discussed. A theoretical relationship between resistivity and thermodynamic measurements was proposed. The theoretical and experimental studies indicate that the dissolution period and the emergence time of peak during hydration process determined by the two methods have a high consistency. Among all the influencing effects, accele