基于与HTPB相互作用共振光散射法测定HgDeterminationofHg2＋.PDF

2012 年第 70 卷 化 学 学 报 Vol. 70, 2012 第 5 期, 643～648 ACTA CHIMICA SINICA No. 5, 643～648 ·研究论文· 基于与 HTPB 相互作用共振光散射法测定 Hg2＋ 王莹莹 谭克俊* 袁 睿 (三峡库区生态环境教育部重点实验室 西南大学化学化工学院 重庆 400715) 摘要 在酸性介质中, 汞(II)与过量溴离子反应生成四溴合汞(II) 阴离子, 后者进一步与 1-十六烷基三苯基溴化膦 ((1-Hexadecyl)triphenylphosphonium Bromide, HTPB)通过静电作用形成离子缔合体, 引起体系的共振光散射信号显著 增强, 最大散射波长位于 291.0 nm 处, 增强的散射信号强度与 Hg2＋浓度在 0.04～1.5 μmol/L 范围内呈线性关系, 检测 限(3σ)为 4.0 nmol/L. 讨论了体系的最佳反应条件及外来物质的干扰, 同时研究了体系的吸收光谱, 并探讨了反应机理. 建立的共振光散射法用于环境水样中 Hg2＋的测定, RSD≤4.42%. 关键词 Hg2＋; 1-十六烷基三苯基溴化磷; 共振光散射 Determination of Hg2＋ by Resonance Light Scattering Technique Based on the Interaction with HTPB Wang, Yingying Tan, Kejun* Yuan, Rui (Key Laboratory of Eco-Environments of Three Gorges Reservoir Region under Ministry of Education of PRC, College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715) Abstract In acidic medium, a resonance light scattering (RLS) analytical method of Hg(II) was established based on the enhanced RLS signal due to the interaction of (1-hexadecyl)triphenylphosphonium bromide (HTPB) and HgBr2 － ion derived from the reaction between mercury ion and excess potassium bromide. 4 The enhanced RLS intensity at 291.0 nm is proportional to the content of mercury(II) in a range of 0.04～1.5 μmol/L. The limit of detection (3σ) is 4.0 nmol/L. In this work, the optimum reaction conditions and the in- te