攀钢含钛高炉渣中钛组分的分离提取研究.pdfVIP

Abstract The Thermodynamic calculation indicates that the various components in blast furnace slag can react with hydrochloric acid spontaneously. By the experimental research, the three-step process route of acid-alkali-acid leaching reaction is adopted to deal with the air-cooled blast furnace slag. The pretreated experiment on the Ti-bearing blast furnace slag cooled in air by the Hydrochloric acid reveals that under the conditions of reaction time keeps for 4 hours, reaction temperature keeps at 100 , the Hydrochloric acid concentration is 6mol/L, acid/slag mass ratio keeps at 1, a higher leaching rate of magnesium, aluminum, calcium and a lower leaching rate of titanium of blast furnace slag can be obtained as well as the preparatory selective impurity is achieved. In the above acid leaching residue, most of magnesium, alumina and calcium are removed off, and the titanium components are relatively enriched. In order to obtain Ti-rich slag, the residue then is treated by alkali leaching process to remove silicon, and the process parameters is optimized. In the process of removing silicon from the residue by alkali, where the most of magnesium, alumina and calcium are removed off, and the titanium components are relatively enriched. It is found that when the reaction temperature keeps at 100 , reaction time keeps for 2h, alkali/slag mass ratio keeps at 0.5, the obtained Ti-enriched slag mainly occurs in the form of perovskite, which contains about 80% TiO2 . In the meanwhile, the silicon components in the filtrate have been recovered by hydrochloric acid treatment process. To study the further enrichment of titanium components, the Ti-enriched slag is purified by t