基于两亲聚合物及离子化的聚偏氟乙烯膜改性研究-仿生材料专业论文.docxVIP

东华大学硕士学位论文 东华大学硕士学位论文 基于两亲聚合物及离子化的聚偏氟乙烯膜改性研究 PAGE PAGE IV 性能的影响。研究发现，通过添加两亲聚合物，PVDF 膜表面的亲 水性得到显著改善，表面粗糙度增加，孔隙率增大，孔径随着聚合 物链长的增加先减小后增大，水通量恢复率明显提高。 （2）以 PDMS 大分子引发剂引发两性离子的前驱体 DMAEMA 单体进行 ATRP 聚合，制备出两亲聚合物 PDMAEMA-PDMS- PDMAEMA 两亲聚合物。并采用 NIPS 法制备 PDMAEMA-PDMS- PDMAEMA/PVDF 共混膜。 研究表明，添加 PDMAMEA-PDMS-PDMAEMA 两亲聚合物后， 膜的形貌发生了明显变化，膜表面孔密度和尺寸增大，表面粗糙度 增加，且随着聚合物添加比例的增加，膜的亲水性，通量及截留率， 恢复率均有显著提升，特别是纯水通量从 105L/m2h 增加到 378L/m2h，截留率从 38.2%增加到 77%，说明添加这种两亲聚合物 后，膜的抗污性能和综合性能显著提高。 （3）将上述 PDMAMEA-PDMS-PDMAEMA/PVDF 共混膜通过 季铵化反应，制备出膜表面和膜孔表面两性离子化的 PVDF 膜。研 究发现，两性离子化对膜形貌也有显著影响，具体为膜主体结构更 加紧凑，膜表突起更加明显。并且相对于两亲聚合物共混膜，两性 离子化膜在各项性能均有明显提升，特别是 BSA 截留率和恢复率分 别达到 94%和 88%，大于季铵化前的 77%和 72%，并且远大于原膜 的 38%和 64%。说明膜两性离子化具有更好的综合改性效果。 关键词：聚偏氟乙烯；两亲聚合物；两性离子化；非溶剂致相分离 PAGE PAGE V MODIFICATION PVDF MEMBRANE VIA AMPHIPHILIC POLYMER AND MEMBRANE SURFACEzwitterionicalization ABSTRCT Poly(vinylidene f luor ide)(PVDF) is a kind of semi-crystalline polymer, which has has excellent performance such as chemical stability, corrosion resistance, heat resistance, radiation resistance, aging resistance et al. In addition, it also has good mechanical property and membrane- forming property, which makes PVDF to be used in water treatment membrane widely. However, the strong hydrophobicity of PVDF leads to stronger driving force in water treatment process and easily to be contaminated, which decreased the membrane service life and increase membrane operate cost. Based on the contamination mechanism, Based on the mechanism of membrane fouling, improving the hydrophilicity of membrane is an important approach to improve the membrane fouling resistance. The method of blending with hydrophilic copolymer is easily operating and producing with large scale. The hydrophilic molecular chains of amphiphilic copolymers would migrate spontaneously to the surface of the membrane forming a hydrophilic layer with long-term stability, which results in improvement of the wetting properties and fouling resistance signif icantly. Furthermore