课件：化学电源工艺学第章.ppt

* systems (Li /SOC12 and Li/SO2) show the best performance throughout the entire temperature range, with the higher-rate Li/SO2 system having the best capacity retention at the very low temperatures. The zinc / air system has a high energy density at normal temperatures, but only at light discharge loads. The lithium / solid-cathode systems, represented by the Li/MnO2 system, show high performance over a wide temperature range, superior to the conventional zinc anode systems. Figure 7.9 shows an improvement in relative position of the denser, heavier battery systems when compared on a volumetric basis. (Note: As stated earlier, these data are necessarily generalized and present e * The relationship is approximately linear when log capacity loss is plotted against log 1/T (temperature, Kelvin). The data assume that the rate of capacity loss remains constant throughout the storage period, which is not necessarily the case with most battery systems. For example, as shown in Chap. 14 for several lithium batteries, the rate of loss tapers off as the storage period is extended. The data are also a generalization of the capability of each battery system under manufacturer-rated conditions because of the many variations in battery design and formulation. The discharge conditions and size also have an influence on charge retention. The capacity loss is usually highest under the more stringent discharge conditions. The ability to store batteries improves as the storage temperature is lowered. Cold storage of batteries is used to extend their shelf life. Moderately cold temperatures, such as 0C, was usually used as freezing could be harmful for some battery systems or designs. As the shelf life of most batteries has been improved, manufacturers are no longer recommending cold storage but suggest room temperature storage is adequate provided that excursions to high temperature is avoided. * * * * * * * * * * 锌锰干电池 松下干电池生产工艺流程 2.8 叠层锌锰电池 （自学） 电池组成 (-)Zn/KOH(aq) /MnO2(+) 额定电压