含苯并二噻吩、苯并噻二唑的聚合物光伏材料的合成及性能分析-高分子化学与物理专业论文.docxVIP

湘潭大 湘潭大学硕士论文 IV IV Abstract Polymer solar cells (PSCs) have attracted considerable attention in recent years due to their potential for low cost, lightweight, and good compatibility with the roll-to-roll process for making ?exible large area devices. In the efforts of researchers, the PCE of BHJ PSCs has achieved 10%. However, to realize the real commercial production, there are still some challenges. In order to broaden the absorption band, enhance the charge carrier mobility, and tune the HOMO and LUMO enery levels of polymer photoconductive materials, we have designed and synthesized a series of new conjugated polymers containing 4,7-dithien-5-yl-2,1,3-benzodiathiazole (DTBT) side groups. The structures of the as-synthesized polymers were all confirmed by 1H-NMR, 13C-NMR, FT-IR and MALDI-TOF. The photophysical and electrochemical properties of the polymers have been investigated systematically by UV-vis spectra, PL spectra, and Cyclic Voltammetry. In addition, the photovoltaic performances of solar cells based on the as-synthesized polymers were measured. The main results are as follows: A new benzodithiophene-based copolymer PTG1 with dithienyl– benzothiadiazole–vinylene side chains has been designed and synthesized. 4,7-dithien-5-yl-2,1,3-benzodiathiazole (DTBT) moiety as an electron-de?cient unit is for the ?rst time to be introduced as side chains attaching the main chain of the polymer via vinylene group. The effect of DTBT side chain on the thermal, optical, electrochemical and photovoltaic properties have been investigated. PTG1 exhibits excellent ?lm forming ability, a deep HOMO energy level, and a good miscibility with PC71BM. Bulk heterojunction polymer solar cells fabricated from PTG1 and PC71BM showed a promising power conversion e?ciency of 4.32%. Three novel copolymers (PT-ID, PT-DTBT and PT-DTBTID) of benzo[1,2-b:4,5-b’]dithiophene and thiophene with different conjugated side groups (1,3-indanedione (ID), 4,7-dithien-5-yl-2,1,3-benzodiathiazole (DT