光电化学池中阴、阳极材料的制备及其光催化分解水的研究-化学专业论文.docxVIP

摘 摘 要 光电化学池中阴、阳极材料的制备及其光催化分解水的研究 光电化学池 光电化学池中阴、阳极材料的制备及其光催化分解水的研究 摘 要 PAGE PAGE IV III III Cu 含量在 6%，光电化学池体系产氢和产氧量分别为 459.0 和 86.2 ?mol g-1。最后， 我们同样给出了在 PEC 体系中的分解水机理。 (3) 通过固态源掺杂法制备了 p 型的光电阴极材料 Cu 掺杂的 TiSi2 半导体，用共 沉淀分解法制备 WO3 光阳极材料，最后经过 Pt 纳米粒子修饰电极并将两个电极串联 起来，形成了光电化学池体系。实验中通过 SEM、AFM、XRD、DRS、光电化学测 试等考察了两种电极材料的结构和光电性质。实验中将光电化学池体系置于紫外可见 光下照射，进行了光催化分解水反应。在反应中，Pt 纳米粒子能够有效的分离和收集 光生电荷，降低了电子空穴的复合率。光电化学池体系产氢和产氧量分别为 171 和 58 ?mol g-1。最后，我们同样给出了在 PEC 体系中的分解水机理。 关键词：半导体；光电极材料；石墨烯；光催化；分解水 作者：吴毅杰 指导老师：杨平教授 Preparation of Photoelectrode Materials in Photoelectrochemical Cell and Their Photocatalytic Water Splitting Properties Abstract Recently, with the development of society, energy shortages and environmental issues have become increasingly prominent and thus seeking for clean and sustainable energy is an urgent task. Solar energy attracts much attention and has been considered as one of the major strategies for solving these problems. Converting solar energy to hydrogen by photocatalytic water splitting seems to be an effective way. Since water splitting system based on TiO2 electrode was discovered by Fujishima in 1972, semiconductor-based photocatalytic system in photoelectrochemical cells gains its popularity. However, the intrinsic drawbacks such as fast chargerecombinationrate and low visible-light absorption limit itspractical application. Thus, many research groups have beenfocusing on developing novel semiconductors with improved photocatalytic efficiencies, such as doping cocatalysis and surface sensitization. The discovery of graphene has opened up a new way to enhance the photocatalytic performance due to its remarkable conductivity and superior electron mobility. In this master’s thesis, we prepared novel photoelectrode materials, using grahene as an excellent electron accepter and mediator. The photocatalytic performance of the materials was carried out in semiconductor photocatalytic system and photoelectrochemical system. The transformation of photoelect