钴铁氧体碳纳米管复合材料的水热合成与表征-材料学专业论文.docxVIP

上海交通大学硕士学位论文ABS 上海交通大学硕士学位论文 ABSTRACT 第 第 PAGE VI 页 万方数据 Hydrothermal Synthesis and Characterization of CoFe2O4/MWNTs Composites ABSTRACT Carbon nanotubes (CNTs) chemistry, as an interdisciplinary field of chemistry research and materials preparation, plays an irreplaceable role in the nano science and technology. CNTs have lots of unique properties, such as one dimensional nano-structure, high aspect ratio, good toughness, excellent electrical and thermal conductivity. Its hardness can be comparable with diamond. These properties entirely grant CNTs potential applications in field emission, high-frequency broadband electromagnetic wave absorption and thermal conductivity, hydrogen storage, and catalysis. It is significantly important to make a study on CNTs composites with high performance which can provide incomparable superiority when used in complex environment. This paper aimed to synthesize spinel ferrite/multi-walled carbon nanotubes (MWNTs) composites. In this study, MWNTs were coated by a layer of nano spinel ferrite particles to modify the magnetic properties and conductivity of MWNTs, hence improving the impedance match and finally enhancing the microwave-absorbing capability. Main work and results were summarized as follows: Hydrothermal synthesis of CoFe2O4 nano-particles was studied by optimizing lots of factors including reaction temperature, Co/Fe ratio in raw materials, precipitator and solvent. The influence of these factors on the phase, morphology, magnetic and electromagnetic parameters of the products was fully investigated. It was found that more orbicular CoFe2O4 nano-particles with larger size were obtained at a higher reaction temperature. CoFe2O4 nano-particles synthesized with NaAc and ethylene glycol (EG)/ water, as the precipitator and solvent respectively, were smaller and in narrower size distribution than in NaOH solution. By comparison, the average size of the CoFe2O4 nano-particles was reduced from 30nm~100nm to 5~10nm. To s