纤蛇纹石酸浸二氧化硅负载TiO2复合材料的结构性能及其降解罗丹明B的实验研究.docxVIP

纤蛇纹石/酸浸二氧化硅负载TiO2复合 材料的结构性能及其降解罗丹明B的实 验研究 曹曦传秀云李爱军黄杜斌 北京大学化学与分子工程学院北京大学地球与空间 科学学院 摘要： 以天然纳米矿物纤蛇纹石和酸浸二氧化硅为载体，钛酸四丁酯为钛源，在室温 条件下采用溶胶-凝胶法，制备了负载TiO2的复合光催化材料。采用气体吸附、 扫描电子显微镜(SEM)、X射线衍射(XRD)等方法对载体和不同温度锻烧得到 的样品进行微观形貌和结构分析，并在紫外光照射下，以10mg/L罗丹明B为目 标污染物评价不同样品的光催化活性。结果表明，750°C锻烧的酸浸二氧化硅负 载TiOz复合材料的光催化性能最好，光照40 min对罗丹明B的去除率达到 91. 57%,载体良好的吸附能力能够促进污染物的降解。 关键词： 纤蛇纹石;酸浸二氧化硅;Ti02;光催化;罗丹明B; 作者简介：曹曦(1990-)，博士，材料及环境矿物学专 业；E-meii 1: xicaochem@pku. edu. on; 作者简介：传秀云，教授，E-ma订:xychuan@pku. edu. cno 收稿日期:2017-08-10 基金：国家自然科学基金资助项目 Structures of Ti02~loaded chrysotile/leached silica composites and the experimental study of their photocatalytic decomposition properties of Rhodamine B CAO Xi CHUAN Xiu—yun LI Ai—jun HUANG Du—bin College of Chemistry and Molecular Engineering, Peking University; School of Earth and Space Sciences, Peking University; Abstract： In this study, Ti02 was loaded onto natural nano mineral chrysotile/leached silica by using hydrolysis of tetrabutyl titanate at room temperature using sol-gel method. The morphological properties and microstructure of the supporters and catalysts at different calcination temperatures were characterized by N2 adsorption/desorption, searming electron microscopy ( SEM) and X-ray diffraction ( XRD) ? The photocatalytic reactivities of these different catalysts were investigated by UV-assisted degradation of 10 mg/L Rhodamine 氏 The resul ts show that the Ti02-loaded sil ica calcined at 750°C exhibits significantly excellent reactivity with the removeil rate of Rhodamine B up to about 91. 57% after irradiation for 40 min, the good adsorption capabilities of the supporters can also contribute to the removal rate of Rhodamine B? Keyword： chrysot订c; lcachcd s订ica; Ti02; photocatalytic; Rhodamine B; Received： 2017-08-10 二氧化钛是一种化学性质稳定、无毒、高效、相对廉价的光催化剂，在有机污染 物降解等环境治理方面应用前景广阔(Chen and Mao, 2007;Hsien e al., 2009; Xue et al., 2012)。在Ti 0?的3种同质多像变体(金红石、锐钛矿、 板钛矿)屮，锐钛矿的催化活性最高，用作光催化剂时，纳米Ti O2粉体的粒径 非常小、极易团聚且难于回收再利用，常造成光催化效率下降、成本上升等问题。 因此，要充分发挥Ti 0?的光催