钴含量和制备方法对铁基非晶合金耐蚀性影响的研究-材料学专业论文.docxVIP

南昌航空大学硕士学位论文 南昌航空大学硕士学位论文 Abstract PAGE PAGE IV Abstract In this paper, Fe24+xCo24-xCr15Mo14C15B6Y2(X=0, 2, 4, 6 and 17) bulk amorphous alloy were fabricated using the non consumable type vacuum arc melting furnace water-cooled copper mold suction casting method, and the amorphous coatings Fe41Co7Cr15Mo14C15B6Y2 were prepared by High Velocity Oxygen-Fuel (HVOF)technology, respectively. The structure and the corrosion morphology of the alloys were characterized using X-ray diffraction (XRD), scanning electron microscope (SEM) and atomic force microscopy (AFM), respectively. The thermodynamic parameters of amorphous alloy have been got by differential thermal analysis (DSC). This article focus on the effects of Co content on the corrosion resistance of Fe-based amorphous alloy and the corrosion resistance test was respectively carried out by neutral salt spray test and electrochemical corrosion experiment. To further discuss the changes of the corrosion characteristics with the addition of Co element, the surface work function distribution, corrosion morphology and elements energy spectrum analysis (EDS) of amorphous alloy have been used in combination. In addition, the rule of the glasses forming ability (GFA) and the corrosion resistance changed with the Co element addition were measured by wedge specimen method and the weight loss law. The corrosion influencing factors between coating and bulk amorphous alloys were investiaged by chemical immersion and electrochemical corrosion method which were based on the surface work function theory. It can be obtained from the structural characteristics analysis of the alloys that the bulk amorphous alloys Fe24+xCo24-xCr15Mo14C15B6Y2(X=0, 2, 4, 6 and 17) and the amorphous coating Fe41Co7Cr15Mo14C15B6Y2 were all proved to be completely amorphous. It shows that when x = 4, the alloy has the widest supercooled liquid region ΔTx and the largest glass-forming ability through differential thermal analysis and wedge sample method