固体氧化物燃料电池双钙钛矿阳极材料分析-材料学专业论文.docxVIP

华 华 中 科 技 大 学 硕 士 学 位 论 文 II II Abstract Double-perovskite Ba2MMoO6 (M = Fe, Co, Mn, Ni) and A2FeMoO6 (A=Ba, Sr, Ca) have been systematically investigated as anode materials for intermediate temperature solid oxide fuel cells (IT-SOFCs). Ba2MMoO6 and A2FeMoO6 were synthesized via sol-gel method. The phase and the structure were ananlyzed. The conductivity, thermal expansion coefficient and thermogravimetric curve of the studied anode materials were tested. Iodometric titration method was used to measure the valence of the M ions in the as-prepared Ba2MMoO6 and hence the formation of crystal oxygen vacancies. Single SOFC cells were fabricated based on electrolyte-supported mode with 300 μm thick La0.8Sr0.2Ga0.83Mg0.17O3?δ (LSGM) as the electrolyte. The power output was tested with Arbin tester, and the anodic overpotential and impedance spectroscopy of the cells were measured with electrochemical workstation. Among the Ba2MMoO6 materials, Ba2FeMoO6 shows the best electrochemical performance with maximum power density of 605 mW cm?2 and electronic conductivity of 196 S cm?1 at 850 °C in H2. Thermal expansion coefficient of Ba2MMoO6 is distributed within the range of (10~18) ×10-6 K-1, which match well with the intermediate-temperature LSGM electrolyte. Thermogravimetric analysis clearly indicates the formation of oxygen vacancies for all the Ba2MMoO6 materials. The power output for the Ba2MMoO6 anodes decreases in the order of M = Fe M = Co M = Mn M = Ni; the overpotential increases in the order of M = Fe M = Co M = Mn M = Ni; and the impedance varies in the order of M = Co M = Fe M = Mn M = Ni. The different performance in this family is ascribed to the difference in conductivity and oxygen vacancy. Our experimental results indicate that the double-perovskites Ba2MMoO6 (M = Fe, Co, Mn, Ni) are potential alternative anode materials for SOFCs. A2FeMoO6 (A = Ba, Sr, Ca) materials show excellent conductivities in H2,