光固化功能材料的制备及性能研究-高分子化学与物理专业论文.docxVIP

光固化功能材料的制备及性能研究 光固化功能材料的制备及性能研究 PREPARATION AND PROPERTIES OF UV-CURING FUNCTIONAL MATERIALS ABSTRACT UV-curing technology is an environmentally friendly technology. The polymer with low surface energy has been rapidly developed and used in many areas due to its unique properties, and the researches on this material has becoming hot spots. The comments on the UV curing technology and low surface energy materials have been remarked. The novel light-cured monomer organofluoro and silicone modified acrylates with the low-surface-energy and better ratio of cost to properties were synthesized through the hydrosilylation reaction. The reaction process was traced and the products were characterized by 1H-NMR and FT-IR technology. The kinetic nature of UV initiated polymerization was examined by real-time infrared spectroscopy (RT-IR). The results indicated that the higher conversion of Si-H bonds in the hydrosilylation is, the higher UV curing rate and the conversion of final double bonds are. The water absorption ratio of light-cured films reduced as increase of dosage of the silicone and organofluoro group, water absorption ratio of curing membranes reduced from 8.1% to 2.3%. The UV-gel with the methyl hydro-silicone oil (10.86%) and perfluoroalkylethyl acrylates ( 0.96%) has a better ratio of cost to properties. The surface energy of silicone grafted octadecyl acrylate 、HDDA can be as low as 26.88mN / m, while the lowest surface energy of silicone grafted lauryl acrylate、HDDA is 40.13 mN / m. Moveover the general performance of silicone-graft- octadecyl acrylate、HDDA was better than that of silicone-graft-lauryl acrylate、 HDDA. In addition, the further heat processes can improve the gel fraction、 hardness、impact strength of UV- curable films,but the water absorption increased. II 河北工业大学硕士学位论文 河北工业大学硕士学位论文 A series of polyurethane acrylates with different structures and different number of functional groups were made up from the reaction of isophorone diisocyanate, diols