含伯胺侧基的水溶性聚合物的快捷精确合成及其功能化衍生-高分子化学与物理专业论文.docxVIP

湘潭大学硕士学位论文 湘潭大学硕士学位论文 II II Abstract Double- or multi-responsive water-soluble polymers are of great interest and attracted much attention in recent years. This thesis gave a comprehensive review on the reactions of low-molecular-weight primary amines, which are suitable for the synthesis of water-soluble polymers. Polymeric amino or amide derivatives were also introduced in this thesis. 2-Aminoethyl methacrylamide hydrochloride and 6-aminohexyl methacrylamide hydrochloride monomers were synthesized. Water-soluble polymers containing primary amino pendant groups were synthesized via aqueous RAFT polymerization under visible light radiation at ambient temperature. The results indicated that this aqueous RAFT polymerization strongly depended on the solution pH. The chain transfer agent moieties were aminolysized rapidly in alkali solutions. Thus this polymerization can only carried out in weak acidic or neutral aqueous solution. Under visible light radiation, this aqueous RAFT polymerization proceeded rapidly at early stage. However, a peak tail of GPC trace was detected at relative high monomer conversions, e.g., over 40-50%. Thus this particular polymerization should be ceased at a low monomer conversion in order to get well-defined polymers. The periodic light-on-off experimental results indicated that this mild visible light could start up and terminate this aqueous RAFT polymerization rapidly. The chain transfer functionalities of PAEMA were decomposed rapidly in neutral or weak basic solutions. However, upon addition of N-(2-acryloyloxyethy) pyrrolidone (NAP), the aminolysis was significantly slowed down. Up to 82.5% chain transfer agent functionalities remains after reacting at 25 oC for 5 h. Michael addition of PAEMA with acrylate,firstly form the single-addition derivatives quickly and secondly form the double-additon derivatives slowly, temperature was not significant with the reaction of Michael addition. These addition derivatives exhibited b