固硫灰的资源化利用分析-材料学专业论文.docxVIP

西南科技大学硕士研究生学位论文第 西南科技大学硕士研究生学位论文 第 PAGE II 页 西南科技大学硕士研究生学位论文第 西南科技大学硕士研究生学位论文 第 PAGE III 页 Abstract In order to realize the energy conservation and pollutant emissions reduction, our country is energetically developing the circulating fluidized bed technology. Circulating fluidized bed coal combustion (CFBC) fly ash were collected from the flue after circulating fluidized bed coal combustion boiler. , which has a great annual emissions each year. This paper intends to study the basic physicochemical properties of CFBC fly ash from Neijiang city in Sichuan province and Bijie city in Guizhou province, and then recycle useful components for its properties, which mainly including recycling iron, modifying CFBC fly ash to improve the adsorption performance and magnetic zeolite synthesized, etc. The research showed that the main component of CFBC fly ash was SiO2, Al2O3 and Fe2O3， which component comprised from 70% to 80%. Also the mineral composition was mainly quartz, anhydrite and hematite. Furthermore, the surface of CFBCfly ash was rough loose, porous. Recovery of iron from CFBC fly ash study has shown that roasting temperature, time, dosage of reductant and the magnetic field intensity has a great influence on the magnetization roasting - magnetic separation process. Results showed that iron with content grade of 51.62% and recovery rate of 86.41% could be obtained under the experimental conditions: － 800℃ of roasting temperature，90 min of roasting time，5% of reducing agent dosage， 200 kA/m of magnetic field intensity of cleaning．At last, we could get iron concentrate with 58.02% of grade and 76.27% of recovery rate by a weak magnetic field strength of 80 Ka/m magnetic separation. XRD showed that the main mineral phase of iron concentrate was magnetite. Research of CFBC fly ash modification showed that solid-liquid ratio, modifier concentration, reaction time and water bath temperature had a greater influence on the process parameters on the