维生素E丁二酸单酯的合成及其在卷烟中的应用-烟草科技.PDF

烟草科技/Tobacco ScienceTechnology 烟草化学/Tobacco Chemistry 2011 年第 11 期（总第292 期） 维生素E丁二酸单酯的合成及其在卷烟中的应用 汤建国，乔丹娜，刘 悍，孟昭宇，牟定荣 红塔烟草（集团）有限责任公司技术中心，云南省玉溪市红塔大道118 号 653100 关键词：维生素E丁二酸单酯；卷烟 摘要：为了提高卷烟主流烟气中维生素E （VE ）释放量，改善卷烟口味，以VE 和丁二酸酐为原料合成了VE 1 13 丁二酸单酯，进行了HPLC 纯度分析和 H NMR ，C NMR 和EI-MS 结构确证，并对添加了合成产物的卷烟 进行了烟气分析和感官评吸试验。结果表明：①合成产物为目标产物——VE 丁二酸单酯，纯度达98% ；② 添加V 丁二酸单酯的卷烟主流烟气中V 释放量增大；③添加V 丁二酸单酯的卷烟烟气刺激性小，吸味品 E E E 质好。V 丁二酸单酯具有增大卷烟主流烟气V 释放量，降低刺激性，改善卷烟吸味的效果。 E E 中图分类号：TS264.3 文献标识码：B 文章编号：1002 - 0861 （2011）11 - 0058 - 04 SynthesisofMonovitaminESuccinateanditsApplicationinCigarettes TANG JIAN⁃GUO, QIAO DAN⁃NA, LIU HAN, MENG ZHAO⁃YU, and MOU DING⁃RONG Technology Center of Hongta Tobacco Group Co., Ltd., Yuxi 653100, Yunnan, China Keywords：Monovitamin E succinate; Cigarette Abstract：In order to increase the delivery of vitamin E (V ) in mainstream cigarette smoke and improve smoking E taste, monovitamin E succinate was synthesized from VE and succinic anhydride, the synthetic was analyzed by HPLC, and identified by 1H NMR, 13C NMR and EI ⁃MS. The smoke analysis and sensory evaluation of the cigarettes spiked with the synthetic were carried out. The results showed that: 1) The synthetic was the target product, monovitamin E succinate, with the purity of 98%. 2) The delivery of VE increased in mainstream smoke of the cigarette spiked with monovitamin E succinate. 3) The smoke irritation of the cigarette containing monovitamin E succinate decreased, and smoking taste improved. monovitamin E succinate has the functions of increasing VE del