含盐高浓度有机废液的蒸发结晶及流化床焚烧处理研究-工程热物理专业论文.docxVIP

浙江大学博士学位论文Abstract 浙江大学博士学位论文 Abstract Great deals of 01_gal】1ic salty liquid WIISl8艄discharged by industries of chemical algill钾rin吕pharmacy and paper making,which嘶easy to lead irreversible environmental pollution．nigh collcenlT砒ioll orgallic liquid wasftt镕calmol be disposed effectively by routine Ue,atrnera methods．h吣．m删i讲I is a very仪啦TIIial method for disposal of these liquid w躯les． H∞VeV既low-melting poim alkali metal and alkaline-earth metal salts bring the problems of agglomeration,fouling,sintering and defluidization duling incineration．So,development and snldy oforganic salty fiquid wastes is strigent need in this field． A n哪wastelvater incineration system with evapomtion-desalination prellealment equipment was put forward to treat organic salty liquid wastes如this dissertation．Volatilization of VOCs(volatile orgllnic compoundn and SVOCs(semi-volatile organic compounds)and desalination were analyzed roundly．Analysis of ion chromatography and COD(elaemical oxygen demand)WaS disemsed．E姗∞cd∞for dedalination of evaporation residues棚incineration of desalinated ofgaIlic：steam Welfle also studied．In addition,kinetics ofevaporation and combustion reactions were inves=ligated． An ion chromatographic method for the determination of alkali mad alkaline-earth metal cations in hi曲conccnll蝴on organic wastewacer WaS developed．n培separ-,aion of cations WaS ∽hieved On∞lonPac CSl2A colunm with 20 Inlal01／L metlumesulfonie∞id舔the eluent The detection w够performed by eonduetivity detectOl-o N114．，K+’M矿arid c一+could be identified within 14 minutes．A Clg cleanup column was used for direct s．amplc injeetion．Thc method is sensitive，selective。and simple,whieh iS convenient to be used for determination ofcations in the smDI伪in the incineration ofliquid w鹄慨Determination ofCoD in tll铭e 0l譬a11ic liquid wastes is dominant for design of bUllleT and estimation of incineration efficiency．High-speed catalytic method for organic liquid with high concentration of chloride ion and Organic compotmds