铜合金分火器表面新型耐高温涂层研究-腐蚀科学与防护技术.PDFVIP

第29 卷 第3 期 腐蚀科学与防护技术腐蚀科学与防护技术 Vol. 29 No. 3 2017 年5 月 CORROSION SCIENCE AND PROTECTION TECHNOLOGY May 2017 铜合金分火器表面新型耐高温涂层研究 程丽文 王 冠 张 冲 谢光荣 廖嘉炜 广东工业大学机电工程学院 广州 510006 摘要 针对铜合金分火器表面长期处于高温状态下，基体表面防护涂层易发生剥落的现象，进行耐高温防护涂 层的研究。使用甲基三甲基硅氧烷(MTMS)、硅溶胶为主要成膜剂，通过电导率变化研究涂料的水解程度。 涂层材料喷涂在铜基体表面，经过烧结形成涂层，其耐热震性能主要与基体表面毛化程度(喷砂粒径)、涂层厚 度、烧结温度和烧结时间有关。实验结果表明，铜合金表面经10~30 目砂毛化处理，涂层厚度控制在20~30 μm ， 烧结时间在10 min ，烧结温度在200 ℃时，获得的涂层耐热震性能最好，在500 ℃下的水冷热震次数达32 次。 关键词 耐高温涂层 耐热震 甲基三甲基硅氧烷(MTMS) 硅溶胶 铜合金 中图分类号 TG 172 文章编号 1002-6495(2017)03-0241-06 A New Type of High Temperature Resistant Coating on Copper Alloy Used for Distributor of Gas Appliance CHENG Liwen, WANG Guan, ZHANG Chong, XIE Guangrong, LIAO Jiawei School of Electromechanical Engineering , Guangdong University of Technology, Guangzhou 510006, China Corresponding: WANG Guan, E-mail: wangguan@gdut.edu.cn Supported by Science and Technology Program of Guangzhou (201604030065 and 201604010041) Manuscript received 2017-03-02, in revised form 2017-04-03 ABSTRACT A new type of high temperature resistant coating with methyltrimethoxysilane (MTMS) and silica solution as main film former, and with appropriate pigments was applied on Cu-alloy, which is used for distributor of gas cooker or gas water heater. The results show that the resistance to thermal shock of the coating is mainly related to the surface roughness of the substrate (grit diameter), the coat- ing thickness as well as the temperature and time of the coating sintering process; an