含氯有机物催化燃烧催化剂的研究-环境化工专业论文.docxVIP

中文摘要含氯有机物(CVOC)燃烧后容易产生有毒副产物，影响大气质量，动植 中文摘要 含氯有机物(CVOC)燃烧后容易产生有毒副产物，影响大气质量，动植 物生长和人类健康。控制CVOC污染已成为大气污染防治的一项重要工作。催 化燃烧法可对污染物彻底氧化分解，能耗低，得到了广泛应用。目前CVOC催 化燃烧的研究热点是，开发出具有良好活性、选择性和稳定性的催化剂。 本文以浸渍法制备了分别以VOx、WO、和MnO。为活性组分，CZ、y-A1203 和Zi02为载体的催化剂。利用XRD、BET、H2．TPR、Raman等表征手段，以 及活性、选择性、稳定性等评价手段，系统研究了载体的性质对催化剂的表面 酸性和氧化能力的影响，以及催化剂表面酸性和氧化能力对其在CVOC催化氧 化反应中的活性、对HCI和C02的选择性和稳定性的影响。 CVOC催化反应分为脱卤反应和氧化反应，其中脱卤反应是控制步骤，由 催化剂B酸位决定。结果表明，500℃焙烧得到的VOx／Ti02催化剂中由于钒物 种与Ti02发生了强相互作用，使其表面具有较多中强B酸位，显示出了较好的 CVOC催化活性。 选择性评价实验结果表明，催化剂MnOx／1,．A1203和MnO。／CZ具有较好的 氧化能力，对C02和C12的选择性较高。通过稳定性评价得知，催化剂 MnOx／)-A1203和MnOx／CZ稳定性较差，SEM．EDS结果表明，上述催化剂表面 形成Mn．CI键，结合上述实验结果可以推断，Mn．CI键的形成可导致活性位减 少从而活性下降，催化剂的抗氯中毒性能主要取决于金属活性位与氯成键的强 度。 关键词： 含氯有机物，催化燃烧，B酸位，氧化能力 AB ABSTRACT Chlorinated volatile organic compounds(cvoc)are harmful in accumulation in the environment and lead to the depletion of the stratospheric ozone layer．A combustion process of CVOC leads to the toxic by-products．Thus，the abatement of CVOC emission is highly important．Catalytic combustion has the advantage of being carried out at relatively low temperature，low energy-consumption，and it can destroy the pollutants rather than merely removes them for recycling elsewhere in the biosphere and is widely employed．Therefore，catalysts with excellent activity,high selectivity for product C02 and HCI，and good stability have gradually become the focus of investigation on CVOC catalytic combustion． With combination of literature and experiment results，it is concluded that CVOC catalytic process consists of dechlorinative section and oxidative section，and the former is control step．Results showed that，VOx厂ri02 and WOx／Ti02 calcined at 500。C exhibited better CVOC catalytic activity,which is attributed to their more strong Bmnsted acid sites than Mno)【／C：Z and MnOx／y-A1203，which is effective in CVOC destruction．However,they have weaker oxidative activity．Thus，the activity of CVOC catalysts depends on its acid property primarily,and the oxidative acitivity secondly． Selectiv