含六氟异丙基聚芳酰胺和聚苯并咪唑的合成及表征-无机化学专业论文.docxVIP

气S 禽. h IIII IIII I I II I II Il r l II II III Y1 944904 摘 要 近年来，随着现代科学技术的迅速发展，对材料的需求越来越高，尤其是 各种高性能和耐高温工程塑料的需求日益迫切。聚芳酰胺和聚苯并咪唑由于结 构多样性和可控性，可以通过引入柔性基团或者三元共聚等改性手段，达到生 成具有耐热性能好等诸多优点的新材料；而含氟聚合物由于突出的综合性能， 越来越受关注。 本文采用双酚AF作为原料，合成出具有六氟异丙烷基的二胺和二元酸化 合物作为聚合单体。 含氟二元胺作为第三单体，加入到4，4’．二氨基二苯醚或者4，4’．二氨基 二苯砜与对苯二甲酰氯的聚合反应中。通过调节第三单体的含量，合成出两个 系列的三元共聚化合物。并利用FT-IR，DSC，TG，WAXD等分析手段对聚 合物进行了结构表征和性能测试。结果表明，随着第三单体含量的增加，共聚 物的溶解度和粘度，以及玻璃化温度等性能都得到改善。 含氟的二元酸作为合成聚苯并咪唑的单体，与含醚基或砜基四胺化合物反 应得到醚基(砜基)聚苯并咪唑。通过FT-IR，TG，WAXD等分析手段对聚 合物进行了结构表征和性能测试。结果表明，此类聚合物的耐热性能好，在热 失重5％时，Td在400℃以上。聚合物溶解性能好，除了溶于浓硫酸外，还 可以溶于其它极性非质子型溶剂。 关键词：聚苯并咪唑、聚芳酰胺、六氟异丙烷基、三元共聚 . .- AbstractIn Abstract In recent years，with the rapid development of modem science and technology,it is highly urgent for US to find some materials which Call tolerates much more dramatic condhions，especially higher temperatures．Due to the controllability and versatility structure of aromatic polyamide and polybenzimidazole，we can generate some new materials winl heat—resistant and many other good qualities by introducing some flexible groups，or ternary copolymer,ete．Because of the comprehensive and prominent performance of fluoropolymer,more and more people’S attention are attracted．In this thesis we successfully synthesized some diamines and diacids with Diphenolic AF勰raW materials to make biprotic acid and biamine compound containing hexafluoroisopropyl groups as monomer ofpolymerization． Containing fluorine binary amine，as the tllird monomer,joined in the solution of 4,4’-diaminodiphenyl ether(DAPE)and 4,4’-diaminodiphenyl sulfone(DDS)and terephthaloyl chloride(TPC)．By adjusting the third monomer’S content,we synthesized tWO series of ternary copolymer compounds successfully．The structures and properties of the compounds were investigated by FT—IIL DSC，TG，XRD etc． The results show that，with the increase of the content of the third monomers，the solubility，viscosity of the products and their glass transition temperatures are improved to some extent．The tlli