含苯氧基、联萘氧基、偶氮苯氧基均三嗪衍生物的制备与表征-高分子化学与物理专业论文.docxVIP

摘要Abstract 摘要 Abstract In this paper,cyanuric chloride which s缸uc嘶containing three chlorine atoms was used as the main raw material for the provision of s-triazine ring．Wah the different reactivities ofthe three chlo血e atoms in cyanuric chloride，a series ofnew s．triazine ring compounds were received by the step-wise reaction through the controlling of the temperature．The s觚cture of these compounds were characterized by Elemental analysis， IR，1H NMR and other research methods，also the solubility,thermal stability properties were studied．It can be summarized as follows． 1．With cyanuric chloride and p-nitrophenol as the raw materials，2,4，6 -3-p—nitrophenoxy-1，3，5-triazine Was prepared by controlling of reaction temperature in acetone and water．Three different methods were used for nitro reduction to obtain 2,4，6． 一aminophenoxy-1，3，5一triazine．With elemental analysis，1H-NMR,IR,TG characterization the products obtained，2,4，6—3-P—nitrophenoxy-1，3，5一tfiazine shows good thermal stability which the initial decomposition temperature was at 430C．Pd／12 hydrazine catalyst system shows a good result in three kinds of reduction methods． 2．With eyanuric chloride and 1，1’BINOL as the raw materials，NaOH as base， cetyltrimethyl ammonium bromide as phase transfer catalyst,poly 2-chloro-4—1，l’-bi naphthyloxy-1，3，5-triazine were prepared through interracial polymerization．Its structure was characterized using uv,IR,1H—NMR,RF,GPC．Also by atomic force microscope(AFM)，the surface of the polymer film Was observed． 3．PCCAB was abtained by the reaction of cyanuric chloride and 4，4’-hydroxyazobenzene using interfacial polymerization．DIATOB w豳got by the reaction of 2-Anilino·4，6一dicholoride·1，3，5一traizine and 4,4-hydroxyazobenzene at 40C in the solvent of acetone and Water．FTIR,1HNMR,TG DSC，UV were used to characterize the structures．And the opticl response property of DIATOB Was studied by UV二Ⅵs．Also the solubility of the two products were studied，PCCAB won’t dissolve even iIl DMF，but DIATO