硅酸盐与含钡硫铝酸盐复合水泥的性能研究-材料物理与化学专业论文.docxVIP

考察指标，研究其和复合水泥的适应性。研究结果表明：磷酸三丁酯和三乙醇胺对复合水泥有较好适应性，适当的掺量可以改善其早期强度。 考察指标，研究其和复合水泥的适应性。研究结果表明：磷酸三丁酯和三乙醇胺 对复合水泥有较好适应性，适当的掺量可以改善其早期强度。 关键词硅酸盐水泥：含钡硫铝酸盐水泥：复合：性能：水化机理 ABSTRACTThis ABSTRACT This paper studied fronf the physical perfomlances of the composite cement system composed of three contents：Ba_bearing sulphoaluminate cement clinkeL gypsum and ordinary Portland cement clinkeL XRD and SEM are used to analyze the hardening mechanism and determine hydrated productions of composite cement， throu曲which hydration mechanisln is discussed in detail． In the paper，the mixing proportion of each domponent is ensured．Study showed that，W11en ordinary Portland cement clinker is 1 O％， Ba-bearing sulphoaluminate cement clinker is about l 5％and gypsum addition is 1 O％achieved better perfomlance index of the composite system．Its compressive stren昏h at ld，3d and 28d age reached 37，8，56．2，76．8 MPa and higher than compressive strength of ordinary Porcland cement 20．6 1 3．7， l 7．7MPa respectively．When two cltnkers complexed，composite cement condensed shorter apparently than ordinary Portland cement and pl_oVided an ef艳ctiVe mealls to soIve the currem problem that cemem condensed slowlyComposite cement also show a good swelling propeny，and the cOntent of 血e swelling property depends On the quantity of Ba—bearing sulphoaluminate cement clinker and gypsum． The hydration heat，chemjcal conlbination wateL XRD and SEM have been used to study the hydration mechanism of composite cement．The resuJts showed that： composite cemcnt hydl_ation heat and hydration rate are hi曲er than ordinary Ponland cement，and the degree of hydratjon of composite cement is hjgher than ordinary Por七1and cement，、v：hich also explains the higll一compressive strength of composite —cement，and condensed fast．The main composite cement hydration products are AFt C—S-H gels and Ca(OH)2，and the quantity of cement hydraIion products varied with the composition of the compos“e cement．Also cement hydration theor)， has been used to study com