固相法制备聚苯胺金属氧化物纳米复合材料-无机化学专业论文.docxVIP

摘要本论文以杂多酸(H4SiWl2040以下简写为SiWl2)为掺杂剂，过硫酸铵为氧化剂， 摘要 本论文以杂多酸(H4SiWl2040以下简写为SiWl2)为掺杂剂，过硫酸铵为氧化剂， 采用固相法制备出了聚苯胺／三氧化二铁纳米复合材料、聚苯胺／三氧化钨纳米复合材料 和聚苯胺／氧化锌纳米复合材料，采用红外光谱、扫描电镜、透射电镜、x一射线粉末衍 射等手段对材料进行了表征，研究并探讨了氧化物形态、用量对聚苯胺纳米复合材料的 影响。论文主要进行了以下几方面的研究工作： 1、以SiWl2为掺杂剂，过硫酸铵为氧化剂，采用固相法成功制备了两种PANI／Fe203 纳米复合材料。并用红外光谱、扫描电镜、透射电镜、x．射线粉末衍射等手段对其进行 了表征。研究得到杂多酸与过硫酸铵摩尔比为1：7时，产物的质量收率最大。 比较了 三氧化二铁形态及用量对复合材料形态的影响并推测了可能的形成机理。测定了复合材 料的电导率。 2、以SiWl2为掺杂剂，过硫酸铵为氧化剂，采用固相法成功制备了PANI／W03纳 米复合材料。并用红外光谱、扫描电镜、透射电镜、x．射线粉术衍射等手段对其进行了 表征。研究得到了杂多酸与过硫酸铵摩尔比为1：7时，产物的质量收率最大。比较了 三氧化钨形态及用量对复合材料形态的影响。测定了复合材料的电导率。 3、以SiWl2为掺杂剂，过硫酸铵为氧化剂，采用固相法成功制备了两种PANI／ZnO 纳米复合材料。并用红外光谱、扫描电镜、透射电镜、x．射线粉末衍射等手段对其进行 了表征。研究了氧化锌形态及用量对复合材料形态的影响。 关键词：聚苯胺；固相法；复合材料；三氧化二铁；三氧化钨；氧化锌 AbstrastIn Abstrast In this paper,polyaniline／Fe203 nanocomposites，polyaniline／W03 nanocomposites and polyaniline／ZnO nanocomposites were prepared by solid phase polymerization method when heterpolyacid(H4SiWl2040)and ammonium persulfate were regarded as doped and oxidizing agent．The structure of the polyaniline／oxide as—nanocomposites were characterized by IR，SEM，TEM，XRD．Futher more，the influencing facters such as the morphology ofoxide and the quantity ofoxide on the morphology ofthe polyaniline／oxide nanocomposites were studied．The main results were obtained as follows： 1．Polyaniline／Fe203 nanocomposites were prepared by solide phase polymerization． The character results showed that the Fe203 was rather encapsulated by the PANI chains， and the highest yield was obtained when the molar of heterpolyacid to ammonium persulfate was 1：7．At the same time，we investigated the influence of the quantity and the mophology of Fe203 on the morphology of polyaniline／Fe203 nanocomposites．The conductivity ofthe polyaniline／Fe203 was determined． 2．Polyaniline／W03 nanocomposites were prepared by solide phase polymerization． The character results showed that the W03 was rather encapsulated by the PANI chains， and the highest yield was obtained when the molar of heterpolyacid to ammonium persulf