固定床催化反应技术制备脂肪酸甲酯工艺的研究-应用化学专业论文.docxVIP

浙江大学硕士学位论文(2007)90叭％，就可以达到99．59％的转化率。而在60(2下二次酯化，达到相同的转 浙江大学硕士学位论文(2007) 90叭％，就可以达到99．59％的转化率。而在60(2下二次酯化，达到相同的转 化率，甲醇总用量为脱臭馏出物的4倍。 关键词：脂肪酸甲酯 酯交换反应 离子交换树脂 固定床 菜籽油 脱臭馏出物 浙江大学硕士学位论文(2007)Abstract 浙江大学硕士学位论文(2007) Abstract Fatty acid methyl esters(FAMEs)are widely used in bioenergy souEce，reaction intermediates，surfactams，and SO on．Using anion exchange resin as catalyst，fatty acid methyl esters call be prepared in a丘xed bed reactor．In this article we have done a lOt ofresearch works on this 6eld． The content of triolein in rapeseed oil is 38．73％．VOVhen the rapeseed oil is totally transesterified耐tll methanol，the content of methyl linolenate，methyl linoleate。 methyl oleate is 16．47％，20．00％and 58．43％，respectively．The total contents of three methyl esters come to 94．89％． We put the resin into the fixed bed reactor(1．62 cm×73．8 cm)and use solid anion exchange resin as catalyst．Then the rapeseed oil Can be transesterified．The rapeseed oil and methanol wffl-e fed separately with two pumps．In this way we can avoid adding auxiliary solvent and instabte flow rate by mechanical stirring．We have examined the steady state in the reactor．The results were as follows：when the ratio of methanol to oil was low and the flow rate Was high，the steady state could be established quickly．However,when the feed volume of rapeseed oil cRme to 60--80 mL，the reactor could always reach steady state． 1k conditions which affect the reaction include temperature．residence time,the ratio ofmethanol to oil．卫艟results were as follows：the optimum temperature WaS 60℃。 which WaS the maximum temperature of the resin．With the ratio of methanol to oil from 3．23 to 8．21．the conversion and the yield increased with the ratio．With the residence time from 5 to 55 minutes，the conversion and the yield increaSed linearly 谢也time，which indicated that the residence time should be lengthened．We used twice and three times transesterification,or connected the outlet of fixed bed with inlet of circulation pumP to lengthen t