基于能带匹配理论设计co_2光催化还原催化剂的研究探究进展_彭辉文档.pdf

2014 33 11 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 3007 CO 2 1 2 2 1 1 1 1 1 2 271018 256600 CO2 CO CO 2 2 CO2 p-n CO CO 2 2 O 613.71O 643.36 A 100066132014 DOI 10.3969/j.issn.1000-6613.2014.11.029 Progress in designing CO photocatalyst based on energy band match theory 2 1 2 2 1 1 1 1 PENG Hui WU Zhihong ZHANG Jianlin LU Jing WU Chenxiao LI Peiqiang YIN Hongzong 1 College of Chemistry and Material Science Shandong Agricultural UniversityTai’an 271018ShandongChina 2Yellow River Delta Jingbo Research of Chemical IndustryBinzhou 256600ShandongChina Abstract In the process of photocatalytic reduction of CO visible light could be absorbed perfectly 2 by the catalyst with a narrowed band gapbut those absorbed light could not be entirely devoted to photocatalytic reduction of CO2as photocatalytic reduction performance is directly related to energy band location and band structure changing has an important influence on redox ability. Beginning with the CO2 photocatalytic reduction basic principlesthis paper is aimed to introduce the basic reduction process of CO2 by semiconductor photocatalystthe decisive role of valence band and conduction band to b