硅丙乳液合成过程及产品性能影响因素的研究-环境工程专业论文.docxVIP

AbstractIn Abstract In this paper，many influence factors of polymerization process and product properties of organic silicone modified acrylic ester emulsion are studied，such as complex emulsifier systems，initiator,organic silicone monomer and acrylic ester monomers，reaction temperature and stirring intensity and SO on．The whole study can be divided into two parts． In the first part，the emulsifier,catalyst and other factors，which can influence the seeded emulsion polymerization of organic silicone modified acrylic ester emulsion are discussed．The purpose，on the one hand，is to chOOSC reasonable emulsifier,catalyst and other raw matedals；on the other hand．is to choose reasonable reaction temperature，stirring intensity and other process conditions． The experimental results shows．if the ratio between MS一1 and OP．10 rangs from 1：1 to 3：1，and the totai dosage of them is about 20％ of Octamethylcyclotetrasiloxane(D4)in qua5ty，we can obtain a kind of stable seeded emulsion of organic silicone modified acrylic ester emulsion．At the same time，if the ratio between MS一1 and Tetramethylammonium Chloride(TMAC)is 1：1．7．the total dosage is about 50％of D4 in quality；the ratio between MS一1 and Cetyltrimethylammonium Chlorine(CTAC)is 7：1，the total dosage is about 25％ of D4 in quality,we Can also obtain stable seeded emulsions．BUt if the complex emulsifier system is made of TMAC and OP．10．MS一1 and Peregal O or CI：AC and Span．80，we can not synthesize any kind of satisfactory seeded emulsions．In addition，the experiment alSO finds that NaOH can not be used as catalyst in the synthesizing process of organic silicone modified acrylic ester emulsion，in contrast，Dodecylbenezene Sulfonic Acid(SDBA)is a good choose． In the second part，the synthesis of organic silicone modified acrylic ester emulsion is discussed．The main process is：the seeded emulsion was put into the reactor,then，the mixture of Methylmethacrylate(MMA)and Butyl Actylate (BA)is dripped successively and gradully into the reactor,w