溶解性微生物产物对土壤中镉析出之影响.DOCVIP

溶解性微生物產物對土壤中鎘析出之影響 The effect of Soluble Microbial Products(SMP) on the release of Cadmium in contaminated soil 研究生：李唯果 Li, wei-kuo 指導教授：郭文健 wen-chien, Kuo 【摘要】 台灣由於工商及各種產業活動密集，許多工業廢水的不當排放，被引用為灌溉用水，而造成農業用地重金屬污染，影響土地之正常利用及國土的整體規畫。因此，經濟有效的土壤復育技術開發是一重要的工作。根據許多研究資料顯示，在微生物活動過程中會釋放出溶解性微生物產物(Soluble Microbial Products,SMP)。此溶解性微生物產物的性質與濃度則根據微生物的種類、生長環境、基質利用速度、溫度、pH、ORP等因素而改變，而溶解性微生物產物值得進一步探討的原因是其具有與重金屬錯合的特性。 本實驗選擇台灣省桃園縣觀音鄉高銀化工附近未受污染土壤，模擬受重金屬鎘污染之狀況，以土壤淋洗的方式，在喜氣及厭氣兩種不同的環境條件下，馴養微生物以產生溶解性微生物產物，探討在不同氧化還原電位下溶解性微生物產物對重金屬移動之影響。研究結果顯示在出流水中溶解性微生物產物的濃度起伏上大致與鎘析出濃度的變化曲線相近，而在鎘析出量方面，以好氧培養的土柱析出鎘總量的26.8％，厭氧培養土柱析出15.3％，以醋酸及無機營養鹽淋洗、並抑制微生物活動的土柱析出鎘總量的22.8％，最低的為單純以無機營養鹽淋洗的土柱，析出總鎘量的1.3％。 關鍵字：溶解性微生物產物 錯合 淋洗 鎘 【Abstract】 Due to heavy economic activities in Taiwan, many illegal discharges of industrial wastes caused the contamination of agricultural land.Thus,development of an economic, efficient, and effective technology to remedy the contaminated soil is very important. Many evidence indicated that Soluble Microbial Products (SMP) were released during microbial activities.The concentration and characteristics of the SMP are functions of the microbial species, growth environment, rate of substrate utilization,temperature,pH and Oxidation/Reduction Pontential, etc. A research was conducted using the uncontaminated soil from Taoyuan County The results show that changes of SMP concentration are close related to the concentration of Cadmium in the reactor effluents. In soil column test, 26.8% of the Cadmium was released from aerobic column,while 15.3% of the Cadmium was released from anaerobic column. Column which microbial activity was inhibited and leached with acetic acid and inorganic nutrients had 22.8% of Cadmium desorbed from the soil. Column leached with only inorganic nutrients had 1.3% of the Cadminm released from the soil. Keywords: Soluble Microbial Products(SMP) , complexation , soil leaching , Cadmium