几种环境污染物电化学传感器的制备及应用研究-化学工程专业论文.docxVIP

万方数据 万方数据 河北科技大学硕士学位论文 H AbstractWith Abstract With the rapid development of science and technology and industrial economy,some typical toxic and harmful organic pollutants have been brought into the environment inevitably,with obtaining large quantities of chemicals to meet the needs of economy, production and life．Some of the organic pollutants have been proved to be carcinogenic，． teratogenic and mutagenic，which cause multiple damage and potential threat to the natural ecological environment and human health． For the electrochemical detection of environmental pollutants，in this paper a series of nano composite modified electrodes were constructed and used for the detellnination of trace organic pollutants in the environment．The main researeh work is deseribed as follows： 1) Construction and application of naphthol based electrochemical sensors A glassy carbon electrode(GCE)modified by graphene oxide(GO)and L—Cysteine (L-Cys)composite film was prepared successfully by the method of dispensing and electro-polymerization．The results showed that the difference of oxidation peak potential between 1-naphthol and 2-naphthol could reach 1 82 my,which was large enough to achieve the simultaneous detection for I-naphthol and 2-naphthol in mixed solution． Differential pulse voltammetry Was adopted to detect naphthol isomer,under the optimized experimental conditions．Two oxidation peak currents showed good linear relationship with the concentration of 1-NAP and 2-NAP in the range form 2岫ol／】■40 rmaol／L and 1 gmol／I_,一O gmol／L，respectively．The detection limits(S／N=3)for 1-NAP and 2-NAP were O．1 9 gmol／L and 0．1 2 J_tmol／L，respectively．The modified electrode showed good stability and reproducibility and had strong anti．interference ability in the detection． 2)A novel sensor for detection of bisphenol A based on graphene and gold and ruthenium(ERGO_Au2Rul)and 13-cyclodextrin(p-CD)composite modified glassy carbon electrode A glassy carbon electrode(GCE)modified by the nanocom