具有多孔结构的刚玉-尖晶石浇注料的制备及其性能-材料科学与工程专业毕业论文.docxVIP

万方数据 万方数据 关键词：刚玉-尖晶石浇注料；泡沫法；多孔结构；抗渣性；导热系数 II Abstract Corundum-spinel castables are widely used as working linings of steel ladles due to their excellent high temperature service performance. However, its high thermal conductivity usually results in a striking decrease of temperature of the molten steel in the steel ladles and leads to high temperature of the shell at the external surface of steel ladles, which increased energy consumption to meet the smelting smoothly. It is well known that the low thermal conductivity of the heat insulation material need to have high porosity. However, for refractories material, it should bring the high apparent porosity and decline the performance of resistance against slag corrosion. Hence, this work means to take advantage of the characteristics of foaming method, which produces uniform pore size distribution, high closed porosity, and controllable bulk density only through changing the foam dosage. Then, introduced the foam to matrix and aggregate corundum-spinel castable, porous corundum-spinel castables were designed and prepared, which ambitiously aimed at reduce the thermal conductivity and improve the thermal shock resistance on the premise that the mechanical strength and slag resistance could be maintained. The work provides theoretical basis for the lightweight of working linings of steel ladles refractory castable. Specific studies and results are as follows: Porous corundum-spinel castable was prepared through introducing the foam to matrix corundum-spinel castable. A systematical investigation on different properties of samples, such as room temperature physical properties, high temperature service performance and thermal conductivity has been taken in this paper and scanning electron microscopy (SEM) was used to characterize the microstructure of samples. The results showed that when the addition foam content is 200 mL/kg, the comprehensive performance was most close to conventional sample, but the thermal conducti