环氧树脂粘结润滑涂层摩擦学特性研究-机械电子工程专业论文.docxVIP

环氧树脂粘结润滑涂层摩擦学特性研究摘要 环氧树脂粘结润滑涂层摩擦学特性研究 摘要 本论文首先通过加热固化试验和热失重分析试验考察了环氧树脂(E54)、 酚醛环氧树脂(F44)以及它们按不同比例混配的复合粘结剂的耐热性能；通 过摩擦磨损试验，探讨了不同粘结剂涂层的摩擦磨损性能和承载能力，综合耐 热性能及摩擦磨损试验结果，获得较好的粘结润滑涂层配方；在此基础上进一 步考察A1203硬质颗粒添加对粘结润滑涂层摩擦磨损性能的影响；进行变温摩 擦磨损试验，探讨了相关涂层在不同温度条件下的摩擦磨损特性。通过光学显 微镜、SEM、能谱成分分析等迸一步研究了粘结润滑涂层的摩擦学特性机理。 F44的添加可以提高E54环氧树脂的耐热性能，随着F44含量的增加，复 合环氧树脂粘结剂的耐热性能逐渐变好；而且由F44与E54混配的复合环氧 树脂粘结润滑涂层具有较好的减摩耐磨性能以及较高的承载能力，当胶黏剂体 系中F44与E54的比例为3：2时，涂层的承载能力及其摩擦学特性最佳；而且 复合环氧树脂粘结润滑涂层的使用温度明显提高，环境温度达到300℃左右 时，仍具有较好的减摩自润滑作用。适宜大小和数量A1203硬质颗粒的添加， 对涂层的减摩性能影响不大，但能在一定程度上提高涂层的耐磨性和承载能 力；然而，较高温度条件下A1203硬质颗粒反而会造成涂层及对偶件的伤害。 干摩擦磨损试验的初始阶段，对偶件与涂层表面微凸体接触，紧密包覆固体润 滑组元的环氧树脂胶黏剂首先与对偶件起作用，减摩润滑效果不佳，随着时间 及载荷的增加，涂层微凸体发生变形、破损而从涂层表面剥离形成磨屑，并逐 渐在涂层表面涂抹形成润滑保护薄膜以及在对偶件表面形成转移层，使得对偶 件与涂层的摩擦转变为润滑薄膜间的摩擦，涂层显示出优良的减摩自润滑性 能。 关键词：环氧树脂，粘结润滑涂层，自润滑，A1203，摩擦，磨损。 Study Study on the Tribological Properties of Epoxy Adhesive Lubricating Coatings Abstract Firstly,the heat resistance of epoxy resin(E54)、phenolic epoxy(F44)and their mixed composite binders in different proportions was investigated by heating solidifying experiments and thermo-gravimetrie analysis．The tribological properties and load—earring capacity of different binder coatings were studied by tribologieal tests．The optimal compositions of adhesive lubricating coatings were determined by integrated analysis of heat resistance and tribological test results of the coatings．In addition，the effect of the filied hard particles of A1203 on the tribological properties of the coatings。The tribologieal performances under different temperatures were also measured．The wear mechanisms of the coatings were analyzed by optical microscope，SEM，energy spectrum analysis． The heat resistance of epoxy resin E54 can be increased by adding F44，i．e．， the heat resistance of composite resin binder increases with the increase of F44 content．The composite lubricating coatings have good wear resistances and high load—earring capacities，and the best tribological properties and load·earring capacity of the coatings app