几种新型二苯并24冠8衍生物的合成及其分子组装体的光物理行为分析-化学;有机化学专业论文.docxVIP

摘要摘 摘要 摘 要 具体介绍了当今超分子化学在分子器件与分子机器领域的研究背景及其最 新的发展动态。总结了近两年来在基于冠醚的超分子领域的离子／分子识别，分 子组装，分子器件和分子机器领域的最新工作，展望了超分子化学的最新发展趋 势，并根据本组的研究基础设计了自己的实验思路和实验方法。利用超分子设计 理念，以带有光活性基团的苯并冠醚衍生物为研究对象，探索其对不同客体的键 合行为和光化学行为。与环糊精，葫芦脲等其他超分子主体配合，设计构筑多种 非共价相互作用协同的超分子组装体，并对其组装过程和光光物理行为进行了初 步的研究。具体内容包括以下四个方面： 1．合成了卟啉修饰二苯并24冠8和C60衍生物，并研究了它们之间的键合 行为和光诱导电子转移行为 2．设计构筑了一个由三联吡啶修饰二苯并24冠8主体、稀土离子和C60衍 生物组成的可控的稀土发光开关。 3：合成了基于锡卟啉和二苯并24冠8的[3]轮烷。 4．设计构筑了多种非共价相互作用协同的新型的非对称杂轮[3]准轮烷并 研究其组装过程和光物理行为。 关键词：超分子化学；冠醚；葫芦脲；分子器件；电荷转移 ABSTRACTFirs4The ABSTRACT Firs4The backgroud and least achievements of supramoleeular chemistry WaS briefly introduced．Then the recent advances in supramolecular chemistry,which involve ion／molecular recognition；molecular self-assembly,molecular device Wele summaried and it also looks into the future of supramoleeular chemistry．According to the concept of supramolecular chemistry,dibenzo[24]一crown-8(DB24C8)derivative bearing terpyridine or porphyrin moiety were prepaired and meir selective binding behaviour as well as photophysical behaviors with fullerene-containing ammonium salt Were further studied．A quaternary complex based on eucurbit[8]uril and 13-cyclodextrin Was constructed and the molecular assembly process WaS a bottom-up approach and a resulting guest-exchange process．The details锄．e弱follows： I．Benefit from the cooperative binding between the strong dectron donor dibenzo[24]erown-8一Porphyrin and accepter C60 Derivatives，Formation of a reasonably stable pseudorotaxane-like complex has been achieved and fully characterized．Based on the reversible assembling／disassembling processes of the Porphyfin-fullerene conjugate，all acid／baSe(or cation／1 8-crown-6) controlled luminescence switch that can turn off／on the PET process from porphyrin to C60 in series Was constructed 2．A novel[2]pseudorotaxane was successfully constructed by the complexafion of dibenzo[24]-crown-8(DB24C8)d耐V撕ve bearing terpyridine moiety谢m lanthanide ion(Tb’十)and fullerene-containing ammonium salt,exhibiting th