密实移动床离子交换过程及装置研究-化工过程机械专业毕业论文.docxVIP

河北 河北工业大学硕士学位论文 密实移动床离子交换过程及装置研究 摘 要 针对固定床离子交换过程中，树脂和设备利用率低的缺点，设计并搭建了密实移动床 离子交换装置。 装置中利用喷射器输送树脂，实验研究了喷射器的相对喉嘴距、喉管与喷嘴面积比及 输送水流量对喷射器输送性能的影响，确定了较佳的喷射器结构和适宜的输送水流量，并 以 KCl 溶液和 NH4HCO3 溶液为原料液，考察了密实移动床吸附及洗脱 K+的效果，以及在 KCl 料液浓度一定的情况下，原料液流量对密实移动床 K+吸附的影响。 结果表明：输送树脂颗粒，喷射器较佳的相对喉嘴距和喉管与喷嘴面积比分别为 7.5 和 2.94，适宜的输送水流量范围为 25~55 L/h。密实移动床中 K+吸附与洗脱操作中，K+的 吸附率高达、树脂利用率、离子交换液浓度以及铵液利用率均比固定床高。KCl 溶液流量 较高时，密实移动床离子交换柱的浓度梯度有所下降，K+吸附率下降。 操作实验过程中设备运行稳定，操作方便，离子交换树脂可以连续及时地转移和输送， 树脂床层能以稳定状态均匀下移而无乱层现象。 关键词：密实移动床，离子交换，喷射器，吸附，洗脱 i 密实 密实移动床离子交换过程及装置研究 THE STUDY ON PACKED MOVING BED EQUIPMENT AND ION EXCHANGE PROCESS ABSTRACT According to the disadvantage of fixed bed ion exchange process is low utilization of resin and equipment, the packed moving bed ion exchange equipment was designed and established. Using ejector to convey the resin, the effects of relative distance of nozzle out to the mixing chamber inlet, area ratio of venturi to nozzle and conveying water flow on conveying properties of the ejector were studied. Better structure of the ejector and appropriate flow of conveying water were proposed. Then with potassium chloride solution and ammonium bicarbonate solution as raw material liquid，the absorption and elution effect of potassium ion with packed moving bed was studied. In addition, the influence by adding liquid raw material flow rate on packed moving bed ion-exchange process was considered. Experimental results show that preferable relative distance of nozzle out to mixing chamber inlet is 7.5 and area ratio of venturi to nozzle is 2.94, 25~55 L/h is the favourable flow of conveying water. In the potassium ion adsorption and elution operation with packed moving bed, absorption rate of potassium, utilization of resin, ion exchange liquid concentration and utilization of ammonia are higher than that of fixed-bed. with an increase in flow rate, the utilization of resin. will be decreased. The running of equipment is stable and operation is easy. Ion exchange resin can be conveyed continuou