具有纳米相复合结构的二元互不溶体系合金的稳定性研究-材料科学与工程专业毕业论文.docxVIP

AbstractIn Abstract In this thesis，the growth behavbr of secondary phase Pb with different volume fractions in A1-Pb nanocomposite alloys and the growth behavior of paramagnetic secondary phase Cu,paramagnetic matrix phase Ag and ferromagnetic matrix phase Fe in Ag-Cu and Fe-Cu nanocomposite alloys under the combined action of temperature field and magnetic field were investigated by X-ray diffractionⅨRD)， scanning electron microscopy(SEM)，and transmission electron microscopy(TEM)． In this thesis，a comprehensive review of the thermal stability of nanocomposite alloys Was carried out．In particular,the thesis introduces the stability of single phase system and namcomposite alloys under temperature field．In addition,the research progress of the thermal stability of nanocrystalline materials under the combined temperature and external fields was introduced． The coarsening of Pb phase with different volume fractions in A1-Pb nanocomposite aNoys follows the coarsening law ofsecondary phase in conventional grain sized composite alloys，that is，the cubic of the average particle radius of Pb phase grows proportional with the annealing time．The coarsening rate o f Pb phase increases distinctly as the volume fraction increases，the variation ofcoarsening rate is greater than the modern Ostwald ripening theoretical prediction in this composition range．The activation energies for coarsening of Pb phase with different volume fractions do not vary with alloy composition and close to the activation energy of grain boundary self-diffusion of solvent matrix AL In nanocomposite alloys，the solute atoms diffuse along the grain boundaries of the solvent matrix and high grain boundary fraction of nanophase matrix promotes the diffusion process． The growth of secondary phase Cu in Ag-Cu and Fe-Cu nanocomposite alloys under the temperature field can still be described by the cubic growth law and the growth of matrix phase follows the kinetic equation describing the grain growth of pure n